Crystal structure of bis(ammonium) bis[pentaaqua(dimethylformamide)zinc(II)] decavanadate tetrahydrate
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F22%3A10444773" target="_blank" >RIV/00216208:11310/22:10444773 - isvavai.cz</a>
Result on the web
<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=PwQvLjUfrG" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=PwQvLjUfrG</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1107/S2056989022003449" target="_blank" >10.1107/S2056989022003449</a>
Alternative languages
Result language
angličtina
Original language name
Crystal structure of bis(ammonium) bis[pentaaqua(dimethylformamide)zinc(II)] decavanadate tetrahydrate
Original language description
The crystalline product (NH4)(2)[Zn(C3H7NO)(H2O)(5)](2)[V10O28] . 4H2O was successfully isolated from an H2O/DMF solvent combination by evaporation at ambient temperature. The salt crystallizes in the P2(1)/n space group. Imidazole, initially used in the synthesis but not present in the product, and DMF solvent appear to affect the synthesis and crystallization as structural-directing agents. In the title compound, the complex cation [Zn(H2O)(5)(DMF)](2+) acts as a counter-ion without being directly coordinated to the decavanadate anion. An extensive framework of hydrogen bonds integrates the whole architecture as evidenced by X-ray crystallography. The polyoxometalate [V10O28](6-) lies on a center of symmetry while the complex cation [Zn(H2O)(5)(DMF)](2+) links three adjacent anions through a set of 2 + 2 + 3 hydrogen bonds.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2022
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Acta Crystallographica. Section E: Crystallographic Communications [online]
ISSN
2056-9890
e-ISSN
2056-9890
Volume of the periodical
78
Issue of the periodical within the volume
5
Country of publishing house
US - UNITED STATES
Number of pages
4
Pages from-to
481-484
UT code for WoS article
000797172000005
EID of the result in the Scopus database
2-s2.0-85132663876