mi-Trithiocyanurato-kappa4N1,S2:N3,S4-bis[(N,N,N',N'',N''-pentamethyldiethylenetriamine-kappa3N,N',N'')zinc(II)] perchlorate monohydrate
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F07%3A00004654" target="_blank" >RIV/61989592:15310/07:00004654 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
mi-Trithiocyanurato-kappa4N1,S2:N3,S4-bis[(N,N,N',N'',N''-pentamethyldiethylenetriamine-kappa3N,N',N'')zinc(II)] perchlorate monohydrate
Original language description
In title compound, [Zn2(C3N3S3)(C9H23N3)2]ClO4.H2O, the dinuclear Zn(II) metal centres are bridged by a trithiocyanurate(3-) anion (ttc), with each centre having a distorted trigonal bipyramidal geometry and bonded to three diethylenetriamine N atoms, and S and N atoms of ttc. The crystal structure is stabilized by O-H ... O, O_H ... S, C-H ... S and C-H ... O interactions connecting the cations, the ClO4- anion and the water molecules.
Czech name
Cloristan mi-trithiokyanurato-kappa4N1,S2:N3,S4-bis[(N,N,N',N'',N''-pentamethyldiethylentriamin-kappa3N,N',N'')zinečnatý] monohydrát
Czech description
V uvedené dvojjaderné sloučenině, [Zn2(C3N3S3)(C9H23N3)2]ClO4.H2O, zinečnaté ionty jsou můstkovány trithiokyanurátovým(3-) aniontem (ttc), s tím že oba centrální atomy mají deformované trigonálně - bipyramidální okolí a jsou koordinovány třemi atomy dusíku z diethylentriaminu, a atomem síry a atomem dusíku z ttc. Krystalová struktura je stabilizována pomocí O-H ... O, O_H ... S, C-H ... S a C-H ... O interakcí spojujících kationty, anion ClO4- a molekuly vody.
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2007
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Acta Crystallographica Section E - Structure Reports Online
ISSN
1600-5368
e-ISSN
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Volume of the periodical
63
Issue of the periodical within the volume
3
Country of publishing house
DK - DENMARK
Number of pages
3
Pages from-to
"m795"-"m797"
UT code for WoS article
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EID of the result in the Scopus database
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