All

What are you looking for?

All
Projects
Results
Organizations

Quick search

  • Projects supported by TA ČR
  • Excellent projects
  • Projects with the highest public support
  • Current projects

Smart search

  • That is how I find a specific +word
  • That is how I leave the -word out of the results
  • “That is how I can find the whole phrase”

Tris(chloristane)(mi(3)-Trithiocyanurato-kappa N-6(1),S-2 : N-3,S-4 : N-5,S-6) tris[(N,N,N',N'',N''-pentamethyldiethylenetriamine-kappa N-3,N',N'')copper(II)]tris(perchlorate)

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F07%3A00004774" target="_blank" >RIV/61989592:15310/07:00004774 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Tris(chloristane)(mi(3)-Trithiocyanurato-kappa N-6(1),S-2 : N-3,S-4 : N-5,S-6) tris[(N,N,N',N'',N''-pentamethyldiethylenetriamine-kappa N-3,N',N'')copper(II)]tris(perchlorate)

  • Original language description

    In the title compound, [Cu-3(C9H23N3)(3)(C3N3S3)](ClO4)(3), the three Cu-II centres, related by the body-diagonal threefold rotation symmetry along [111], are bridged by a trithiocyanurate(3-) anion (ttc), with each centre having a considerably distortedtrigonal - bipyramidal geometry and bonded to three N atoms of a tridentate N,N,N',N'',N''-pentamethyldiethylenetriamine ligand, and one S and N atoms of the ttc ligand. The secondary structure is estabilized by a variety of weak hydrogen bonds of the type C-H...O connecting the cation and perchlorate anions.

  • Czech name

    Tris(chloristan)(mi(3)-trithiokyanurato-kappa N-6(1),S-2 : N-3,S-4 : N-5,S-6) tris[(N,N,N',N'',N''-pentamethyldiethylentriamin-kappa N-3,N',N'')měďnatý

  • Czech description

    V uvedené sloučenině, [Cu-3(C9H23N3)(3)(C3N3S3)](ClO4)(3), tři atomy Cu(II) jsou můstkovány trithiokyanurátovým(3-) aniontem (ttc), každý centrální atom je v deformovaném trigonálně - bipyramidálním uspořádání koordinován třemi atomy z tridentátního ligandu N,N,N',N'',N''-pentamethyldiethylentriaminu a jedním atomem síry a jedním atomem dusíku z ligandu ttc. Sekundární struktura je stabilizována pomocí slabých vodíkových vazeb typu C-H...O, které spojují kation a chloristanové anionty.

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2007

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Acta Crystallographica Section E - Structure Reports Online

  • ISSN

    1600-5368

  • e-ISSN

  • Volume of the periodical

    63

  • Issue of the periodical within the volume

    6

  • Country of publishing house

    DK - DENMARK

  • Number of pages

    2

  • Pages from-to

    "m1742"-"m1743"

  • UT code for WoS article

  • EID of the result in the Scopus database