(mu(3)-Trithiocyanurato-kappa(6) N-1,S-2 : N-3, S-4 : N-5, S-6) tris[(N,N,N ',N '',N ''-pentamethyldiethylenetriamine-kappa(3) N,N ',N '') zinc(II)] tris(perchlorate)
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F07%3A00023838" target="_blank" >RIV/00216224:14310/07:00023838 - isvavai.cz</a>
Alternative codes found
RIV/61989592:15310/07:00004782
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
(mu(3)-Trithiocyanurato-kappa(6) N-1,S-2 : N-3, S-4 : N-5, S-6) tris[(N,N,N ',N '',N ''-pentamethyldiethylenetriamine-kappa(3) N,N ',N '') zinc(II)] tris(perchlorate)
Original language description
In the title compound, [ Zn-3( C3N3S3)(C9H23N3) 3]( ClO4) 3, the three Zn-II centres, related by the body-diagonal threefold symmetry along [ 111], are bridged by a trithiocyanurate(3-) anion (ttc), with each centre having a distorted trigonal bipyramidal geometry and bonded by three N atoms of a tridentate N, N, N', N", N"-pentamethyldiethylenetriamine ligand, and one S and one N atoms of the ttc ligand. The secondary structure is stabilized by a variety of non-bonding C-H . . O interactions, connecting the cation and perchlorate anions.
Czech name
(mu(3)-Trithiocyanurato-kappa(6) N-1,S-2 : N-3, S-4 : N-5, S-6) tris[(N,N,N ',N '',N ''-pentamethyldiethylenetriamine-kappa(3) N,N ',N '') zinc(II)] tris(perchlorate)
Czech description
V článku je detailně popisována krystalová struktura titulního zinečnatého komplexu.
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2007
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Acta Crystallographica Section E: Structure Reports Online
ISSN
1600-5368
e-ISSN
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Volume of the periodical
63
Issue of the periodical within the volume
5
Country of publishing house
GB - UNITED KINGDOM
Number of pages
3
Pages from-to
"M1411"-"M1413"
UT code for WoS article
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EID of the result in the Scopus database
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