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[mu]-Trithiocyanurato-[kappa]4N1,S2:N3,S4-bis[(N,N,N',N'',N''-pentamethyldiethylenetriamine-[kappa]3N,N',N'')zinc(II)] perchlorate monohydrate

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F07%3A00021954" target="_blank" >RIV/00216224:14310/07:00021954 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    [mu]-Trithiocyanurato-[kappa]4N1,S2:N3,S4-bis[(N,N,N',N'',N''-pentamethyldiethylenetriamine-[kappa]3N,N',N'')zinc(II)] perchlorate monohydrate

  • Original language description

    In the title compound, [Zn2(C3N3S3)(C9H23N3)2]ClO4.H2O, the dinuclear ZnII metal centres are bridged by a trithiocyanurate(3-) anion (ttc), with each centre having a distorted trigonal bipyramidal geometry and bonded to three diethylenetriamine N atoms,and an S and an N atom of ttc. The crystal structure is stabilized by O-H...O, O-H...S, C-H...S and C-H...O interactions connecting the cations, the ClO4- anions and the water molecules.

  • Czech name

    Monohydrát dvojjaderného pentamethyldiethylentriamino-zinečnatého komplexu s kyselinou trithiocyanurovou a chloristanovým iontem

  • Czech description

    V titulním dvojjaderném komplexu, [Zn2(C3N3S3)(C9H23N3)2]ClO4.H2O, jsou 2 centrální Zn(II) můstkově propojeny trithiocyanurovým trianionem (ttc). Každý z centrálních atomů zaujímá geometrii porušené trojboké bipyramidy a je navázán na 3 N atomy diethylenetriaminu a S a N atom ttc. Krystalová struktura je dále stabilizována nevazebnými interakcemi O-H...O, O-H...S, C-H...S a C-H...O spojujícími kationy, ClO4- aniony a molekuly vody.

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2007

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Acta Crystallographica Section E

  • ISSN

    1600-5368

  • e-ISSN

  • Volume of the periodical

    63

  • Issue of the periodical within the volume

    3

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    3

  • Pages from-to

    "m795"-"m797"

  • UT code for WoS article

  • EID of the result in the Scopus database