Porphyrins Intercalated in Zn/Al and Mg/Al Layered Double Hydroxides: Properties and Structural Arrangement
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11320%2F10%3A10081986" target="_blank" >RIV/00216208:11320/10:10081986 - isvavai.cz</a>
Alternative codes found
RIV/61388980:_____/10:00346803 RIV/61388955:_____/10:00346803 RIV/00216208:11310/10:10081986
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Porphyrins Intercalated in Zn/Al and Mg/Al Layered Double Hydroxides: Properties and Structural Arrangement
Original language description
The arrangement of porphyrin molecules in the interlayer space of layered double hydroxides (LDH) has been studied by a combination of experimental techniques and molecular dynamics simulations. Intercalation of 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrins (TPPS) into ZnRAl and MgRAl LDH hosts led to a gallery height of about 15.5A ° that is comparable with the size of the porphyrin molecules. The porphyrin sulfonate groups are located at about 4A ° from the center of the hydroxide layers that is consistent with hydrogen bonding interactions between the sulfonate groups and OH groups of the layers. The aromatic ring system in the middle of the gallery is rather disordered. A large number of in-plane diffraction lines suggests that the rigidity of the porphyrin framework has a beneficial effect on the layer ordering.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2010
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Chemistry of Materials
ISSN
0897-4756
e-ISSN
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Volume of the periodical
22
Issue of the periodical within the volume
8
Country of publishing house
US - UNITED STATES
Number of pages
10
Pages from-to
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UT code for WoS article
000276817200011
EID of the result in the Scopus database
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