Inorganic-Organic Hybrid Materials: Layered Zinc Hydroxide Salts with Intercalated Porphyrin Sensitizers

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11320%2F10%3A10082010" target="_blank" >RIV/00216208:11320/10:10082010 - isvavai.cz</a>

Alternative codes found

RIV/61388980:_____/10:00349658 RIV/61388955:_____/10:00349658

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Inorganic-Organic Hybrid Materials: Layered Zinc Hydroxide Salts with Intercalated Porphyrin Sensitizers

Original language description

Layered materials provide a two-dimensional interlayer space suitable for accommodating molecules with a designed functionality. In this study, inorganic-organic hybrids were prepared by intercalation of anionic porphyrin sensitizers into the host structure of layered zinc hydroxide salts. The inorganic host offers stabilization and protection, whereas the guest species provide the photofunction. The properties and arrangement of porphyrin molecules in the interlayer space were studied by a combinationof experimental techniques and molecular simulations. Intercalation of porphyrins led to a gallery height that is comparable with the size of porphyrin molecules. Molecular simulations showed that the interlayer space is filled with disordered porphyrinunits.The porphyrin sulfonate groups interact with the brucite-like layers via dominant electrostatic interactions similarly to layered double hydroxides.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

<a href="/en/project/GAP207%2F10%2F1447" target="_blank" >GAP207/10/1447: Photoactive hybrid materials</a><br>

Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2010

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Physical Chemistry C

ISSN

1932-7447

e-ISSN

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Volume of the periodical

114

Issue of the periodical within the volume

39

Country of publishing house

US - UNITED STATES

Number of pages

8

Pages from-to

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UT code for WoS article

000282209800034

EID of the result in the Scopus database

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