Insight into the Structure of Layered Zinc Hydroxide Salts Intercalated with Dodecyl Sulfate Anions

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11320%2F14%3A10290885" target="_blank" >RIV/00216208:11320/14:10290885 - isvavai.cz</a>

Alternative codes found

RIV/61388980:_____/14:00438719 RIV/61388955:_____/14:00438719

Result on the web

<a href="http://dx.doi.org/10.1021/jp508499g" target="_blank" >http://dx.doi.org/10.1021/jp508499g</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1021/jp508499g" target="_blank" >10.1021/jp508499g</a>

Result language

angličtina

Original language name

Insight into the Structure of Layered Zinc Hydroxide Salts Intercalated with Dodecyl Sulfate Anions

Original language description

This Article presents the systematic experimental and theoretical investigation of the structural arrangements of dodecyl sulfate (DS) anions in the interlayer space of layered zinc hydroxide salts (LZH-DS) and of the structure of zinc hydroxide layers,with a detailed description of the zinc ions coordination environment. As-prepared, well-crystalline LZH-DS has a basal spacing of 31.5 angstrom. After treatment with methanol at room temperature, zinc hydroxide layers shrank to form two new layered phases with basal spacings of 26.4 and 24.7 angstrom. The shrinking was accompanied by a decrease in the content of DS anions in the interlayer space, indicating a change in the alignment of the intercalated anions and a decrease in the charge density of thezinc hydroxide layers. The latter effect was assessed by the atomic pair distribution function (PDF) analysis of powder X-ray diffraction patterns, revealing the successive removal of Zn ion tetrahedra from the hydroxide layers, with the

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CI - Industrial chemistry and chemical engineering

OECD FORD branch

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Project

<a href="/en/project/GA13-05114S" target="_blank" >GA13-05114S: Hexanuclear molybdenum clusters with tunable photophysical properties</a><br>

Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2014

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Physical Chemistry C

ISSN

1932-7447

e-ISSN

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Volume of the periodical

118

Issue of the periodical within the volume

46

Country of publishing house

US - UNITED STATES

Number of pages

11

Pages from-to

27131-27141

UT code for WoS article

000345474000081

EID of the result in the Scopus database

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