Intercalates of Strontium Phenylphosphonate with Alcohols - Structure Analysis by Experimental and Molecular Modeling Methods
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11320%2F15%3A10314737" target="_blank" >RIV/00216208:11320/15:10314737 - isvavai.cz</a>
Alternative codes found
RIV/61389013:_____/15:00443463 RIV/00216275:25310/15:39899472
Result on the web
<a href="http://dx.doi.org/10.1002/ejic.201403069" target="_blank" >http://dx.doi.org/10.1002/ejic.201403069</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/ejic.201403069" target="_blank" >10.1002/ejic.201403069</a>
Alternative languages
Result language
angličtina
Original language name
Intercalates of Strontium Phenylphosphonate with Alcohols - Structure Analysis by Experimental and Molecular Modeling Methods
Original language description
Alcohol intercalated strontium phenylphosphonates were prepared by the addition of alcohols to an aqueous solution of strontium phenylphosphonate (SrPhP). These intercalates are unstable and de-intercalate spontaneously at ambient conditions. For the complete elucidation of their structure, a combination of a single-crystal X-ray diffraction and molecular modeling was used. The structure of the host layers in methanol (SrPhP center dot MeOH) and ethanol (SrPhP center dot EtOH) intercalates is composed of strontium atoms, which are eight-coordinate by oxygen atoms of the phosphonato groups and of water molecules. The structures of SrPhP center dot MeOH and SrPhP center dot EtOH differ in the orientation of the phenyl rings. The alcohol molecules residein the cavities formed by the phenyl rings and are coordinated to the Sr atoms of the host layer through their oxygen atoms. On the basis of the structure of SrPhP center dot EtOH, the structures of propanol and butanol intercalates and o
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CI - Industrial chemistry and chemical engineering
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA14-13368S" target="_blank" >GA14-13368S: 2D structures based on metal phosphonates: relationships between arrangement and properties studied by experimental and calculation methods</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
European Journal of Inorganic Chemistry
ISSN
1434-1948
e-ISSN
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Volume of the periodical
2015
Issue of the periodical within the volume
9
Country of publishing house
DE - GERMANY
Number of pages
10
Pages from-to
1552-1561
UT code for WoS article
000351435100009
EID of the result in the Scopus database
2-s2.0-84923013546