Intercalation of 1,n-diols into strontium phenylphosphonate: How the shape of the host layers influences arrangement of the guest molecules

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11320%2F15%3A10314738" target="_blank" >RIV/00216208:11320/15:10314738 - isvavai.cz</a>
Alternative codes found
RIV/61389013:_____/15:00448267 RIV/00216275:25310/15:39899473
Result on the web
<a href="http://dx.doi.org/10.1016/j.jcis.2015.08.043" target="_blank" >http://dx.doi.org/10.1016/j.jcis.2015.08.043</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jcis.2015.08.043" target="_blank" >10.1016/j.jcis.2015.08.043</a>

Result language
angličtina
Original language name
Intercalation of 1,n-diols into strontium phenylphosphonate: How the shape of the host layers influences arrangement of the guest molecules
Original language description
Strontium phenylphosphonate intercalates with 1,n diols (n = 2-4, 6-8) having general formula SrC6H5PO3 center dot x(HO(CH2)(n)OH)center dot yH(2)O were prepared by precipitation from strontium phenylphosphonate solution and the corresponding diols. Prepared compounds exhibit a very good stability at ambient conditions. The intercalates were characterized by X-ray diffraction, thermogravimetry and elemental analysis. Thanks to the existence of free spaces among the benzene rings the diols exhibit a peculiar intercalation behavior. This behavior is explained on the basis of molecular simulation, which facilitated to elucidate the arrangement of the diol (guest) molecules in the specifically shaped space between the layers of the host material. From thestructural point of view the intercalates can be divided into two subgroups: (i) intercalates with 1,2- to 1,4-diols and (ii) intercalates with 1,6- to 1,8-diols. The alkanediols of the first group are immersed in the free spaces among th
Czech name
—
Czech description
—

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CI - Industrial chemistry and chemical engineering
OECD FORD branch
—

Project
<a href="/en/project/GA14-13368S" target="_blank" >GA14-13368S: 2D structures based on metal phosphonates: relationships between arrangement and properties studied by experimental and calculation methods</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Similar results(10)