Reduction of silver ions to silver with polyaniline/poly(vinyl alcohol) cryogels and aerogels
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11320%2F18%3A10439666" target="_blank" >RIV/00216208:11320/18:10439666 - isvavai.cz</a>
Alternative codes found
RIV/61389013:_____/18:00490816
Result on the web
<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=.S54ZmffIa" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=.S54ZmffIa</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s11696-017-0374-6" target="_blank" >10.1007/s11696-017-0374-6</a>
Alternative languages
Result language
angličtina
Original language name
Reduction of silver ions to silver with polyaniline/poly(vinyl alcohol) cryogels and aerogels
Original language description
The macroporous conducting polymer cryogels were prepared by the oxidation of aniline hydrochloride in the frozen aqueous solutions of poly(vinyl alcohol) at - 24 A degrees C. Corresponding polyaniline aerogels supported with poly(vinyl alcohol) have been obtained after thawing of cryogels followed by freeze-drying. Silver was deposited on the composites using the ability of polyaniline to reduce silver ions after the immersion in silver nitrate solutions. Swollen cryogels were coated only on the surface with macroscopic silver particles due to the closed-pore structure in cryogels and limited penetration of silver ions into macropores. The diffusion of silver ions to freeze-dried aerogels was better and further improved by vacuum treatment. Silver microcubes were produced in the pores, the weight fraction of silver in dry composites being typically several per cent, a maximum 13 wt%. The conductivity of the aerogels compressed to pellets depended on the processing and the highest value was 0.27 S cm(-1). The aerogels containing silver were characterized in detail with Raman spectroscopy.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10301 - Atomic, molecular and chemical physics (physics of atoms and molecules including collision, interaction with radiation, magnetic resonances, Mössbauer effect)
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Chemical Papers
ISSN
0366-6352
e-ISSN
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Volume of the periodical
72
Issue of the periodical within the volume
7
Country of publishing house
DE - GERMANY
Number of pages
10
Pages from-to
1619-1628
UT code for WoS article
000435829800005
EID of the result in the Scopus database
2-s2.0-85048809572