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Reduction of silver ions to silver with polyaniline/poly(vinyl alcohol) cryogels and aerogels

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F18%3A00490816" target="_blank" >RIV/61389013:_____/18:00490816 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216208:11320/18:10439666

  • Result on the web

    <a href="http://dx.doi.org/10.1007/s11696-017-0374-6" target="_blank" >http://dx.doi.org/10.1007/s11696-017-0374-6</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1007/s11696-017-0374-6" target="_blank" >10.1007/s11696-017-0374-6</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Reduction of silver ions to silver with polyaniline/poly(vinyl alcohol) cryogels and aerogels

  • Original language description

    The macroporous conducting polymer cryogels were prepared by the oxidation of aniline hydrochloride in the frozen aqueous solutions of poly(vinyl alcohol) at − 24 °C. Corresponding polyaniline aerogels supported with poly(vinyl alcohol) have been obtained after thawing of cryogels followed by freeze-drying. Silver was deposited on the composites using the ability of polyaniline to reduce silver ions after the immersion in silver nitrate solutions. Swollen cryogels were coated only on the surface with macroscopic silver particles due to the closed-pore structure in cryogels and limited penetration of silver ions into macropores. The diffusion of silver ions to freeze-dried aerogels was better and further improved by vacuum treatment. Silver microcubes were produced in the pores, the weight fraction of silver in dry composites being typically several per cent, a maximum 13 wt%. The conductivity of the aerogels compressed to pellets depended on the processing and the highest value was 0.27 S cm−1. The aerogels containing silver were characterized in detail with Raman spectroscopy.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10404 - Polymer science

Result continuities

  • Project

    <a href="/en/project/GA16-02787S" target="_blank" >GA16-02787S: Conducting polymer cryogels</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2018

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Chemical Papers

  • ISSN

    0366-6352

  • e-ISSN

  • Volume of the periodical

    72

  • Issue of the periodical within the volume

    7

  • Country of publishing house

    SK - SLOVAKIA

  • Number of pages

    10

  • Pages from-to

    1619-1628

  • UT code for WoS article

    000435829800005

  • EID of the result in the Scopus database

    2-s2.0-85048809572