Tuning the morphology of sputter-deposited platinum catalyst: From compact layers to dispersed nanoparticles
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11320%2F23%3A10468342" target="_blank" >RIV/00216208:11320/23:10468342 - isvavai.cz</a>
Result on the web
<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=eaDhh2O5R8" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=eaDhh2O5R8</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.surfin.2023.103079" target="_blank" >10.1016/j.surfin.2023.103079</a>
Alternative languages
Result language
angličtina
Original language name
Tuning the morphology of sputter-deposited platinum catalyst: From compact layers to dispersed nanoparticles
Original language description
A comprehensive study on adjusting the morphology of sputter-deposited platinum was performed. Platinum was deposited under various Ar pressure ranging from 0.3 to 3.2 Pa using a conventional magnetron system as well as at 57 Pa using a gas aggregation cluster source integrated into the magnetron sputtering system. The morphology and structure of deposited layers were characterized with a broad portfolio of characterization techniques such as scanning electron microscopy, transmission electron microscopy, grazing incidence small angle X-ray scattering and X-ray diffraction. The results revealed a continuous evolution of the Pt layer morphology from a thin-film-like layer of tightly packed Pt nanoparticles to a deposit composed of dispersed particles of 5-7 nm in size as the Ar pressure increased. The electrochemically active surface area of deposited Pt, as calculated from cyclic voltammograms, increased with deposition pressure from 11.7 m(2)center dot g(Pt)(-1) to 22.3 m(2)center dot g(Pt)(-1) and 24 m(2)center dot g(Pt)(-1) for Pt deposited at 0.3, 3.2 and 57 Pa, respectively. This increase in active sites was reflected in a significant improvement in the mass activity of platinum exemplary confirmed using a methanol electrooxidation reaction.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10305 - Fluids and plasma physics (including surface physics)
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2023
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Surfaces and Interfaces
ISSN
2468-0230
e-ISSN
2468-0230
Volume of the periodical
40
Issue of the periodical within the volume
Aug
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
7
Pages from-to
103079
UT code for WoS article
001058542500001
EID of the result in the Scopus database
2-s2.0-85163012883