Biological Activity and Molecular Structures of Bis(benzimidazole) and Trithiocyanurate Complexes

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14110%2F15%3A00083400" target="_blank" >RIV/00216224:14110/15:00083400 - isvavai.cz</a>

Alternative codes found

RIV/62156489:43210/15:43908451 RIV/00216305:26620/15:PU115173

Result on the web

<a href="http://dx.doi.org/10.3390/molecules200610360" target="_blank" >http://dx.doi.org/10.3390/molecules200610360</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.3390/molecules200610360" target="_blank" >10.3390/molecules200610360</a>

Result language

angličtina

Original language name

Biological Activity and Molecular Structures of Bis(benzimidazole) and Trithiocyanurate Complexes

Original language description

1-(1H-Benzimidazol-2-yl)-N-(1H-benzimidazol-2-ylmethyl)methanamine (abb) and 2-(1H-benzimidazol-2-ylmethylsulfanylmethyl)-1H-benzimidazole (tbb) have been prepared and characterized by elemental analysis. These bis(benzimidazoles) have been further usedin combination with trithiocyanuric acid for the preparation of complexes. The crystal and molecular structures of two of them have been solved. Each nickel atom in the structure of trinuclear complex [Ni3(abb)3(H2O)3ttc)](ClO4)3?3H2O?EtOH (1), where ttcH3 = trithiocyanuric acid, is coordinated with three N atoms of abb, the N,S donor set of ttc anion and an oxygen of a water molecule. The crystal of [(tbbH2)(ttcH2)2(ttcH3)(H2O)] (2) is composed of a protonated bis(benzimidazole), two ttcH2 anions, ttcH3 and water. The structure is stabilized by a network of hydrogen bonds.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

FI - Traumatology and orthopaedics

OECD FORD branch

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Project

<a href="/en/project/ED1.1.00%2F02.0068" target="_blank" >ED1.1.00/02.0068: Central european institute of technology</a><br>

Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2015

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Molecules

ISSN

1420-3049

e-ISSN

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Volume of the periodical

20

Issue of the periodical within the volume

6

Country of publishing house

CH - SWITZERLAND

Number of pages

17

Pages from-to

10360-10376

UT code for WoS article

000357992700054

EID of the result in the Scopus database

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