Synthesis, X-ray and Mössbauer study of iron(II) complexes with trithiocyanuric acid (ttcH3). The X-ray structures of [Fe(bpy)3](ttcH).2bpy.7H2O and [Fe(phen)3](ttcH2)(ClO4). 2CH3OH.2H2O.

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F04%3A00011588" target="_blank" >RIV/00216224:14310/04:00011588 - isvavai.cz</a>

Alternative codes found

RIV/61389030:_____/04:00000296 RIV/61989592:15310/04:00002142 RIV/61989592:15310/04:00009893

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Synthesis, X-ray and Mössbauer study of iron(II) complexes with trithiocyanuric acid (ttcH3). The X-ray structures of [Fe(bpy)3](ttcH).2bpy.7H2O and [Fe(phen)3](ttcH2)(ClO4). 2CH3OH.2H2O.

Original language description

Iron(II) complexes with a combination of nitrogen-donor ligands and trithiocyanuric acid (ttcH3) of the composition [Fe(bpy)2(ttcH)].2H2O (1), [Fe(bpy)3](ttcH).2bpy.7H2O (2), [Fe(terpyCl)2](ttcH2)2.H2O (3), [Fe(phen)2(ttcH)].2H2O (4), [Fe(nphen)2(ttcH)].4H2O (5) and [Fe(phen)3](ttcH2)(ClO4).2CH3OH.2H2O (6), where bpy = 2,2-bipyridine, terpyCl = 4-chloro-2,2:6,2-terpyridine, phen = 1,10-phenanthroline, nphen = 5-nitro-1,10-phenanthroline, have been prepared. The compounds, except for 6, have been characterized by elemental analysis, 57Fe Mössbauer, IR and UVVis spectroscopies. It has been found that the trithiocyanurate ion is either coordinated to the metal centre (1, 4 and 5) or situated outside the inner coordination sphere of the iron(II) ion (2, 3and 6). The X-ray crystal structures of complexes 2 and 6 demonstrate that the ligands enforce a distorted octahedral geometry on the FeII ions with monoanionic 2 and dianionic 6 forms of uncoordinated trithiocyanuric acid. Density-functi

Czech name

Syntéza, RTG a Mössbauer. studie Fe(2) komplexů trithiokyanurové kyseliny. RTG struktury [Fe(bpy)3](ttcH).2bpy.7H2O a [Fe(phen)3](ttcH2)(ClO4). 2CH3OH.2H2O

Czech description

Fe(2) komplexy s N-donorovými ligandy a trithiokyanurovou kyselinou byly studovány element. analýzou, 57Fe Mössbauer, IR a UV-Vis spektroskopiemi a metodami RTG difrakce.

Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

<a href="/en/project/GA203%2F02%2F0436" target="_blank" >GA203/02/0436: Application of Crystallographic Databases in Scientific Practice</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2004

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Polyhedron

ISSN

0277-5387

e-ISSN

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Volume of the periodical

23

Issue of the periodical within the volume

14

Country of publishing house

GB - UNITED KINGDOM

Number of pages

10

Pages from-to

2193-2202

UT code for WoS article

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EID of the result in the Scopus database

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