Syntheses and X-ray structures of heteroleptic octahedral Mn (II)-xanthato complexes involving N-donor ligands

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F15%3A33156178" target="_blank" >RIV/61989592:15310/15:33156178 - isvavai.cz</a>
Alternative codes found
RIV/00216224:14310/15:00084852
Result on the web
<a href="http://dx.doi.org/10.1080/00958972.2015.1102228" target="_blank" >http://dx.doi.org/10.1080/00958972.2015.1102228</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1080/00958972.2015.1102228" target="_blank" >10.1080/00958972.2015.1102228</a>

Result language
angličtina
Original language name
Syntheses and X-ray structures of heteroleptic octahedral Mn (II)-xanthato complexes involving N-donor ligands
Original language description
A series of octahedral manganese(II) complexes involving xanthates and N-donor ligands, [Mn (S(2)COiBu)(2)(phen)] (1), [Mn(S(2)COiBu)(2)(2,2'-bpy)] (2), [Mn(S(2)COnPr)(2)(phen)] (3), [Mn(S(2)COnPr)(2) (2,2'-bpy)] (4), [Mn(S2COMe)(2)(2,2'-bpy)] (5), [Mn(S(2)COnPr)(2)(4,4'-bpy)](n), and [Mn-2(S(2)COnPr)(4) (4,4'-bpy)(3)] (6) (phen = 1,10-phenanthroline, bpy - bipyridine) was prepared. Complexes were characterized by elemental analysis, FTIR spectroscopy, TG/DSC analysis, and single-crystal X-ray diffraction. The structures are built of monomeric molecules of the complexes, except for 6 with the 4,4'-bipyridine ligand, which contains a binuclear complex and 1D polymeric zigzag chain in one crystal.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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