Synthesis and X-Ray Structures of Zinc(II) and Cadmium(II) Heteroleptic Complexes Involving 1,1-Dithiolate and N-Donor Ligands
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F14%3A33153123" target="_blank" >RIV/61989592:15310/14:33153123 - isvavai.cz</a>
Alternative codes found
RIV/00216224:14310/14:00075888
Result on the web
<a href="http://dx.doi.org/10.1080/10426507.2014.902825" target="_blank" >http://dx.doi.org/10.1080/10426507.2014.902825</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1080/10426507.2014.902825" target="_blank" >10.1080/10426507.2014.902825</a>
Alternative languages
Result language
angličtina
Original language name
Synthesis and X-Ray Structures of Zinc(II) and Cadmium(II) Heteroleptic Complexes Involving 1,1-Dithiolate and N-Donor Ligands
Original language description
2,2-bipy = 2,2-bipyridine) ligands, of the composition [Cd(S2COnPr)2(2,2-bipy)] (1), [Cd(S2COnPr)2(1,10-phen)] (2), [Cd(S2P(OEt)2)2(2,2-bipy)] (3), [Cd(S2 P(OEt)2)2(1,10-phen)] (4), [Zn(S2COnPr)2(2,2-bipy)] (5), [Zn(S2COnPr)2(1,10-phen)] (6), [Zn(S2P(OEt)2)2(2,2-bipy)] (7), and [Zn(S2P(OEt)2)2(1,10-phen)] (8) was prepared. The complexes (1-8) were characterized by elemental analysis and single-crystal X-ray analysis. X-ray structures revealed that the coordination geometries vary from octahedral (complexes 1-4), through square-pyramidal (complexes 5 and 6) to tetrahedral (complexes 7 and 8), depending on a combination of the central metal atoms and the corresponding S-donor and N-donor ligands. Similarities and discrepancies among the individual molecular structures as well as noncovalent contacts stabilizing crystal structures are discussed in more detail.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
S - Specificky vyzkum na vysokych skolach
Others
Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Phosphorus, Sulfur, and Silicon and the Related Elements
ISSN
1042-6507
e-ISSN
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Volume of the periodical
189
Issue of the periodical within the volume
10
Country of publishing house
GB - UNITED KINGDOM
Number of pages
14
Pages from-to
1-14
UT code for WoS article
000345368100005
EID of the result in the Scopus database
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