Adamantane-Like Aluminum Amide-Phosphate from Alumazene
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F02%3A00007041" target="_blank" >RIV/00216224:14310/02:00007041 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Adamantane-Like Aluminum Amide-Phosphate from Alumazene
Original language description
A dealkylsilylation reaction between alumazene [2,6-(i-Pr)2C6H3NAlMe]3 (1) and tris(trimethylsilyl) ester of phosphoric acid (2) in a 1:3 molar ratio provides the heteroadamantane molecule (MeAl)[2,6-(i-Pr)2C6H3N]3{Al[OP(OSiMe3)3]}2(O3POSiMe3) (3). Compound 3 was characterized by analytical and spectroscopic methods and its molecular structure was established by a single-crystal X-ray diffraction experiment. Moreover, trialkyl and triaryl phosphates, and dialkyl phosphonates react with 1 at elevated temperature to afford an intractable mixture of products. The reaction of phosphonic acids with 1 proceeds under decomposition to yield 2,6-diisopropylaniline and aluminophosphonates.
Czech name
Adamantane-Like Aluminum Amide-Phosphate from Alumazene
Czech description
A dealkylsilylation reaction between alumazene [2,6-(i-Pr)2C6H3NAlMe]3 (1) and tris(trimethylsilyl) ester of phosphoric acid (2) in a 1:3 molar ratio provides the heteroadamantane molecule (MeAl)[2,6-(i-Pr)2C6H3N]3{Al[OP(OSiMe3)3]}2(O3POSiMe3) (3). Compound 3 was characterized by analytical and spectroscopic methods and its molecular structure was established by a single-crystal X-ray diffraction experiment. Moreover, trialkyl and triaryl phosphates, and dialkyl phosphonates react with 1 at elevated temperature to afford an intractable mixture of products. The reaction of phosphonic acids with 1 proceeds under decomposition to yield 2,6-diisopropylaniline and aluminophosphonates.
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA203%2F01%2F1533" target="_blank" >GA203/01/1533: New Nonaqueous Routes to Phosphate, Silicate, Hybrid, and Oxide Materials</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2002
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Inorg. Chem.
ISSN
0020-1669
e-ISSN
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Volume of the periodical
41
Issue of the periodical within the volume
25
Country of publishing house
US - UNITED STATES
Number of pages
5
Pages from-to
6914
UT code for WoS article
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EID of the result in the Scopus database
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