A Supramolecular Hexameric Ring from Alumazene and Methylsulfonate

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F06%3A00015819" target="_blank" >RIV/00216224:14310/06:00015819 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
A Supramolecular Hexameric Ring from Alumazene and Methylsulfonate
Original language description
A dealkylsilylation reaction of alumazene [2,6-( i-Pr)2C6H3NAlMe]3 (1) with trimethylsilyl methylsulfonate in a 1:2 molar ratio in toluene afforded a supramolecular cyclic hexamer {Me[2,6-( i-Pr)2C6H3NAl]3- (O3SMe)2}6 (2) composed of six intact alumazenerings and possessing two types of bridging sulfonate groups. Changing the reagent molar ratio to 1:3 caused the third sulfonate to partially substitute the last alumazene methyl group in an eta2 fashion and introduced a disorder in the crystal lattice.
Czech name
Supramolekulární hexamerní cyklus z alumazenu a methylsulfonátu
Czech description
Dealkylsilylační reakce alumazenu [2,6-( i-Pr)2C6H3NAlMe]3 (1) s trimethylsilyl methylsulfonátem v molárním poměru 1:2 v toluenu poskytla supramolekulární cyklický hexamer {Me[2,6-( i-Pr)2C6H3NAl]3- (O3SMe)2}6 (2).

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
<a href="/en/project/GA203%2F04%2F0296" target="_blank" >GA203/04/0296: Sonochemical synthesis of oxide and phosphate materials</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year
2006
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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