Mixed ligand complexes of platinum(II) and palladium(II) with cytokinin-derived compounds Bohemine and Olomoucine: X-ray structure of [Pt(BohH(+)-N7)Cl-3].9/5H(2)O {Boh=6-(benzylamino)-2-[(3-(hydroxypropyl)-amino]-9-isopropylpurine, Bohemine}

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F03%3A00008013" target="_blank" >RIV/00216224:14310/03:00008013 - isvavai.cz</a>
Alternative codes found
RIV/61389030:_____/03:56033120 RIV/61989592:15310/03:00001533 RIV/61989592:15410/03:00001533
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
Mixed ligand complexes of platinum(II) and palladium(II) with cytokinin-derived compounds Bohemine and Olomoucine: X-ray structure of [Pt(BohH(+)-N7)Cl-3].9/5H(2)O {Boh=6-(benzylamino)-2-[(3-(hydroxypropyl)-amino]-9-isopropylpurine, Bohemine}
Original language description
The new square-planar Pt(II) and Pd(II) complexes with cytokinin-derived compounds Bohemine and Olomoucine, having the formulae [Pt(BohH(+))Cl3].H2O (1), [Pt(Boh)(2)Cl-2].3H(2)O (2), [Pt(Boh-H)Cl(H2O)2].H2O (3), [Pt(OloH(+))Cl-3].H2O (4), [Pd(BohH(+))Cl-3].H2O (5), [Pd(Boh)Cl-2(H2O)] (6), [Pd(Boh-H)Cl(H2O)].EtOH (7) and [Pd(OloH(+))Cl-3].H2O (8), where Boh=6(benzylamino)-2-[(3-(hydroxypropyl)amino]-9-isopropylpurine and Olo=6-(benzylamino)-2-[(2-(hydroxyethyl)amino]-9-methylpurine, have been synthesized. The complexes have been characterized by elemental analyses, IR, FAB+ mass, H-1, C-13 and Pt-195 NMR spectra, and conductivity data. The molecular structure of the complex [Pt(BohH(+)-N7)Cl-3].9/5H(2)O has been determined by an X-ray diffraction study.Results from physical studies show that both Bohemine and Olomoucine are coordinated to transition metals through the N(7) atom of purine ring in all the complexes. The prepared compounds have been tested in vitro for their possible cyto
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2003
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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