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Preparation, spectral properties and structures of Cu(LN)xNi(CN)4 (LN = N-methylated derivates of 1,2-diaminoethane; x = 1,2)

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F03%3A00008643" target="_blank" >RIV/00216224:14310/03:00008643 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216224:14310/03:00021159

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Preparation, spectral properties and structures of Cu(LN)xNi(CN)4 (LN = N-methylated derivates of 1,2-diaminoethane; x = 1,2)

  • Original language description

    From the water - methanol solution of Cu(II) - LN - [Ni(CN)4]2- (1:2:1) (LN = N, N-dimethylethylenediamine (dmen); N,N'-dimethylethylenediamine (bmen); N,N,N',N'-tetramethylethylenediamine (tmen) ) were isolated three new compounds: Cu(dmen)2Ni(CN)4 (CDNC), Cu(bmen)2Ni(CN)4 (CBNC) and Cu(tmen)Ni(CN)4 (CTNC). The result of X-ray structure analysis have shown that CDNC exhibits one-dimensional structure and consists of infinite quasi-linear 2,2-TT chains [-NC-Ni(CN)2-CN-Cu(dmen)2-] running parallel with the c axis. The results of elemental analyses and IR spectra suggest similarities between CBNC and CDNC with respect to the composition and structure. On the other hand, CTNC has only one tmen ligand in the copper atom co-ordination sphere, and as a consequence, other type of structure containing terminal and bridging cyano groups has been formed. The results of EPR spectroscopy indicate the local symmetry at unpaired electron centre is (almost) uniaxial for CDNC, rhombic for CBNC, and un

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2003

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Solid State Phenomena

  • ISSN

    1012-0394

  • e-ISSN

  • Volume of the periodical

    90-91

  • Issue of the periodical within the volume

    1

  • Country of publishing house

    CH - SWITZERLAND

  • Number of pages

    6

  • Pages from-to

    323-328

  • UT code for WoS article

  • EID of the result in the Scopus database