Preparation, spectral properties and structures of Cu(LN)xNi(CN)4 (LN = N-methylated derivates of 1,2-diaminoethane; x = 1,2)
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F03%3A00008643" target="_blank" >RIV/00216224:14310/03:00008643 - isvavai.cz</a>
Alternative codes found
RIV/00216224:14310/03:00021159
Result on the web
—
DOI - Digital Object Identifier
—
Alternative languages
Result language
angličtina
Original language name
Preparation, spectral properties and structures of Cu(LN)xNi(CN)4 (LN = N-methylated derivates of 1,2-diaminoethane; x = 1,2)
Original language description
From the water - methanol solution of Cu(II) - LN - [Ni(CN)4]2- (1:2:1) (LN = N, N-dimethylethylenediamine (dmen); N,N'-dimethylethylenediamine (bmen); N,N,N',N'-tetramethylethylenediamine (tmen) ) were isolated three new compounds: Cu(dmen)2Ni(CN)4 (CDNC), Cu(bmen)2Ni(CN)4 (CBNC) and Cu(tmen)Ni(CN)4 (CTNC). The result of X-ray structure analysis have shown that CDNC exhibits one-dimensional structure and consists of infinite quasi-linear 2,2-TT chains [-NC-Ni(CN)2-CN-Cu(dmen)2-] running parallel with the c axis. The results of elemental analyses and IR spectra suggest similarities between CBNC and CDNC with respect to the composition and structure. On the other hand, CTNC has only one tmen ligand in the copper atom co-ordination sphere, and as a consequence, other type of structure containing terminal and bridging cyano groups has been formed. The results of EPR spectroscopy indicate the local symmetry at unpaired electron centre is (almost) uniaxial for CDNC, rhombic for CBNC, and un
Czech name
—
Czech description
—
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
—
Result continuities
Project
—
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2003
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Solid State Phenomena
ISSN
1012-0394
e-ISSN
—
Volume of the periodical
90-91
Issue of the periodical within the volume
1
Country of publishing house
CH - SWITZERLAND
Number of pages
6
Pages from-to
323-328
UT code for WoS article
—
EID of the result in the Scopus database
—