Cyano-bridged bimetallic complexes of copper(II) with tetracyanonickelate(II). Crystal structure of [Cu(dpt)Ni(CN)(4)]

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F01%3A00001646" target="_blank" >RIV/61989592:15310/01:00001646 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Cyano-bridged bimetallic complexes of copper(II) with tetracyanonickelate(II). Crystal structure of [Cu(dpt)Ni(CN)(4)]

Original language description

Five new complexes of composition [Cu(dpt)Ni(CN)(4)] (1) (dpt = dipropylenetriamine), [Cu(dien)Ni(CN)(4)].2H(2)O (2) (dien = diethylenetriamine), [Cu(N,N'-dimeen)Ni(CN)(4)].H2O (3) (N,N' dimeen = N,N'-dimethylethylenediamine), [Cu(N,N dimeen)Ni(CN)(4)].H2O (4) (N,N-dimeen N,N dimethylethylenediamine) and [Cu(trimeen)Ni(CN)(4)] (5) (trimeen=N,N,N'-trimethylethylenediamine) have been obtained by the reactions of the mixture of Cu(ClO4)(2).6H(2)O, appropriate amine and K-2[Ni(CN)(4)] in water and have beencharacterized by IR and UV-Vis spectroscopies and magnetic measurements. The crystal structure of [Cu(dpt)Ni(CN)(4)] (1) has been determined by single-crystal X-ray analysis. The structure of 1 consists of a one-dimensional polymeric chain -Cu(dpt)-NC-Ni(CN)(2)-CN Cu(dpt)- in which the Cu(II) and Ni(11) atoms are linked by CN groups. The nickel atom is four coordinate with four cyanide carbon atoms (two cyano groups are terminal and two cyano groups (in cis fashion) are bridged) in a sq

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2001

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Polyhedron

ISSN

0277-5387

e-ISSN

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Volume of the periodical

20

Issue of the periodical within the volume

28

Country of publishing house

GB - UNITED KINGDOM

Number of pages

6

Pages from-to

3301-3306

UT code for WoS article

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EID of the result in the Scopus database

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