Use of multi-N-donor ligands for preparation of organic-inorganic hybrid materials: Crystal structures of ionic [M(aepn)2][Ni(CN)4].H2O and polymeric M(aepn)Ni(CN)4 (M = Zn(II), Cd(II); aepn = N-(2-aminoethyl)-1,3-propanediamine)

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F07%3A00022526" target="_blank" >RIV/00216224:14310/07:00022526 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Use of multi-N-donor ligands for preparation of organic-inorganic hybrid materials: Crystal structures of ionic [M(aepn)2][Ni(CN)4].H2O and polymeric M(aepn)Ni(CN)4 (M = Zn(II), Cd(II); aepn = N-(2-aminoethyl)-1,3-propanediamine)

Original language description

From aqueous systems M-aepn-[Ni(CN)4]2- (M = Zn, Cd; aepn = [N-(2-aminoethyl)-1,3-propanediamine]) using variable M: aepn molar ratios [Cd(aepn)2] [Ni(CN)4].H2O (1), Cd(aepn)Ni(CN)4 (2), [Zn(aepn)2][Ni(CN)4].H2O (3) and Zn(aepn)Ni(CN)4 (4) have been prepared and identified. Single crystal X-ray structure analyses have shown that the crystal structures of 1 and 3 are ionic and are built up of [Zn(aepn)2]2+ and [Cd(aepn)2]2+ cations, respectively, [Ni(CN)4]2- anions and water molecules of crystallisation,and 2 and 4 exhibit polymeric structures. In the three-dimensional structure of 2 two crystallographically independent tetracyanonickellate anions are placed on inversion centres and exhibit connectivities two and four, respectively, with bridging cyanogroups linking cadmium and nickel atoms. Octahedrally coordinated cadmium atom exhibits connectivity three. In one-dimensional structure of 4 [Ni(CN)4]2- anions and [Zn(aepn)]2+ cations are linked via bridging cyano ligands. Both buildin

Czech name

Užití násobných N-dovorových ligandů k přípravě hybridních organicko-anorganických materiálů: Krystalové struktury [M(aepn)2][Ni(CN)4].H2O a M(aepn)Ni(CN)4 (M = Zn(II), Cd(II); aepn = N-(2-aminoethyl)-1,3-propanediamine)

Czech description

Titulní sloučeniny byly připraveny z vodného systému M-aepn-[Ni(CN)4]2- (M = Zn, Cd; aepn = [N-(2-aminoethyl)-1,3-propanediamine]) za použití rozličných molár. poměrů M:aepn. Supramolekulární kontakty, do kterých se vzniklé komplexy zapojují, byly studovány metodami rtg strukturní krystalografie.

Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2007

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Molecular Structure

ISSN

0022-2860

e-ISSN

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Volume of the periodical

842

Issue of the periodical within the volume

1-3

Country of publishing house

GB - UNITED KINGDOM

Number of pages

8

Pages from-to

117-124

UT code for WoS article

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EID of the result in the Scopus database

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