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Toxicity increases in ice upon containing monochlorophenols upon photolysis: environmental consequences

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F04%3A00010048" target="_blank" >RIV/00216224:14310/04:00010048 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Toxicity increases in ice upon containing monochlorophenols upon photolysis: environmental consequences

  • Original language description

    The toxic effects of photoproducts formed upon the photolysis of 2- and 4-chlorophenol (CP) frozen solutions in polycrystalline ice phase were determined with a bacterial luminescence test (Vibrio fisheri), and in vitro biomarker assay for dioxin-like effects (inductions of AhR-dependent luciferase in H4IIE-luc cells), and compared to the toxic effects of products of the same photoreaction in aquatic phase. Coupling photoproducts formed in ice samples (3-chlorobiphenyl-2,4-diol and 3-chlorobiphenyl-2,2-diol from 2-CP photolysis, and 5-chlorobiphenyl-2,4-diol from 4-CP photolysis) were found to be more toxic to Vibrio fisheri than parent CPs and elicited significant inductions of dioxin-like effects (the effective concentrations EC50 ~ 3 10-5 mol L-1 corresponded to known weaker ligands of AhR, such as non-planar polychlorinated biphenyls (PCBs) or polycyclic aromatic hydrocarbons (PAHs)). To complete the picture, a photoproduct formed from 4-CP (5-chlorobiphenyl-2,4-diol) was synthesiz

  • Czech name

    Nárůst toxicity po ozařování chlorfenolů v ledu: environmentální souvislosti

  • Czech description

    Nárůst toxicity po ozařování chlorfenolů v ledu: environmentální souvislosti

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    DN - Environmental impact on health

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2004

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Environmental Science & Technology

  • ISSN

    0013-936X

  • e-ISSN

  • Volume of the periodical

    38

  • Issue of the periodical within the volume

    10

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    6

  • Pages from-to

    2873-2878

  • UT code for WoS article

  • EID of the result in the Scopus database