Synthesis of 3,3'-substituted[2]staffane derivatives and NMR study of their inclusion complexes with beta-cyclodextrin in water

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F04%3A00010131" target="_blank" >RIV/00216224:14310/04:00010131 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Synthesis of 3,3'-substituted[2]staffane derivatives and NMR study of their inclusion complexes with beta-cyclodextrin in water

Original language description

Derivatives of bicyclo[1.1.1]pentante (BCP) I were recognized as very interesting class of compounds due to their structural features. For example, BCP cage represents a basic construction module for rigid rod like molecules . [n]staffanes II, the fundamental part of suggested molecular size construction set1. Having the set of predefined properties with appropriate tools of supramolecular chemistry in hand, one might be able to construct novel molecular materials. Since practically useful synthesis of[1.1.1]propellane had been found, synthetic aspects of BCP chemistry became relatively developed recently2. On the other hand, there is little known about supramolecular chemistry of BCP derivatives so far. Inspired with Berg et al. (cf.3) describing complexation of bicyclo[2.2.2]octane derivatives with cyclodextrins (CD) and with CD-based pseudo-rotaxane model4 in our minds, we focused our interest to the host-guest chemist

Czech name

Synthesis of 3,3'-substituted[2]staffane derivatives and NMR study of their inclusion complexes with beta-cyclodextrin in water

Czech description

Derivatives of bicyclo[1.1.1]pentante (BCP) I were recognized as very interesting class of compounds due to their structural features. For example, BCP cage represents a basic construction module for rigid rod like molecules . [n]staffanes II, the fundamental part of suggested molecular size construction set1. Having the set of predefined properties with appropriate tools of supramolecular chemistry in hand, one might be able to construct novel molecular materials. Since practically useful synthesis of[1.1.1]propellane had been found, synthetic aspects of BCP chemistry became relatively developed recently2. On the other hand, there is little known about supramolecular chemistry of BCP derivatives so far. Inspired with Berg et al. (cf.3) describing complexation of bicyclo[2.2.2]octane derivatives with cyclodextrins (CD) and with CD-based pseudo-rotaxane model4 in our minds, we focused our interest to the host-guest chemist

Type

D - Article in proceedings

CEP classification

CC - Organic chemistry

OECD FORD branch

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Project

<a href="/en/project/ME%20571" target="_blank" >ME 571: Substituted bicyclo /1.1.1./ pentans and únú staffants</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2004

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Article name in the collection

Chemické listy, IV. Mezioborové setkání mladých biologů,

ISBN

0009 - 2770

ISSN

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e-ISSN

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Number of pages

1

Pages from-to

274

Publisher name

Česká společnost chemická

Place of publication

Praha

Event location

Devět skal - Žďárské vrchy

Event date

Jun 9, 2004

Type of event by nationality

CST - Celostátní akce

UT code for WoS article

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