Preparation of Monomeric LAl(NH2)2 The First Main-Group Metal Diamide Containing Two Terminal NH2 Groups in the Presence of a N-heterocyclic Carbene as HCl Acceptor

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F04%3A00011409" target="_blank" >RIV/00216224:14310/04:00011409 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Preparation of Monomeric LAl(NH2)2 The First Main-Group Metal Diamide Containing Two Terminal NH2 Groups in the Presence of a N-heterocyclic Carbene as HCl Acceptor

Original language description

We have presented a novel method for preparing aluminum amides and hydroxides from the corresponding chlorides. The main byproduct - N,N-di-tbutylimidazolium chloride - can be easily separated from the product by filtration and recycled to the free base.LAl(NH2)2 is to the best of our knowledge the first monomeric main-group metal diamide containing two terminal NH2 groups.

Czech name

Příprava monomerního LAl(NH2)2

Czech description

Příprava monomerního LAl(NH2)2

Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

<a href="/en/project/GA203%2F01%2F1533" target="_blank" >GA203/01/1533: New Nonaqueous Routes to Phosphate, Silicate, Hybrid, and Oxide Materials</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2004

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Angewandte Chemie International Edition

ISSN

1433-7851

e-ISSN

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Volume of the periodical

43

Issue of the periodical within the volume

16

Country of publishing house

DE - GERMANY

Number of pages

4

Pages from-to

2142-2145

UT code for WoS article

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EID of the result in the Scopus database

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