The Reaction of [P3N3Cl4(NH2)2] with [HN(POCl2)2]; the Crystal Structure of a Phosphazenium Salt [P3N3HCl4(NH2)2]+ [N(POCl2)2]-.
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F97%3A00003795" target="_blank" >RIV/00216224:14310/97:00003795 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
The Reaction of [P3N3Cl4(NH2)2] with [HN(POCl2)2]; the Crystal Structure of a Phosphazenium Salt [P3N3HCl4(NH2)2]+ [N(POCl2)2]-.
Original language description
P3N3Cl5(NH2) in high purity and good yield can be obtained by the reaction of P3N3Cl4(NH2)2 with gaseous HCl in acetonitrile If diethylether or dichlormethane is used as a solvent, a salt-like compound [P3N3Cl4H(NH2)2+Cl- is formed as a microcrystallineproduct instead of P3N3Cl5(NH2). The crystal structure of P3N3Cl5(NH2)was determined by X-ray structure analysis. Vibrational spectra and thermic behavior of both P3N3Cl5(NH2)and [P3N3Cl4H(NH2)2+Cl- are also briefly discussed.
Czech name
Reakce P3N3Cl4(NH2)2 s HCl: krystalová struktura P3N3Cl5(NH2).
Czech description
Reakcí P3N3Cl4(NH2)2 s HCl v acetonitrilu lze připravit ve vysokém výtěžku P3N3Cl5(NH2), jehož krystalová struktura byla určena RTG strukturní analýzou. Při použití diethyletheru nebo dichlormethanu vzniká při této reakci fosfazeniová sůl [P3N3Cl4H(NH2)2]+Cl-. Diskutována byla vibrační spektra obou látek a studováno jejich termické chování.
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA203%2F95%2F1190" target="_blank" >GA203/95/1190: Structure and Bonding in the Compounds of Nitrogen,Phosphorus,Sulfur and Selenium and in the Complexes of Fe,Co,and Ni with N,P,S-Ligands</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
1997
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Zeitschrift für anorganische und allgemeine Chemie [Bd. 380 (1971) -]
ISSN
0044-2313
e-ISSN
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Volume of the periodical
1997
Issue of the periodical within the volume
623
Country of publishing house
DE - GERMANY
Number of pages
5
Pages from-to
637
UT code for WoS article
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EID of the result in the Scopus database
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