New isostructural ethylenediammonium diphosphates (NH3(CH2)2NH3)2[Me(HP2O7)2 * 2 H2O] [Me = Co, Ni]: X-ray crystal structure and vibrational spectroscopy

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F06%3A00018630" target="_blank" >RIV/00216224:14310/06:00018630 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

New isostructural ethylenediammonium diphosphates (NH3(CH2)2NH3)2[Me(HP2O7)2 * 2 H2O] [Me = Co, Ni]: X-ray crystal structure and vibrational spectroscopy

Original language description

New ethylenediammonium diphosphates (NH3(CH2)(2)NH3)(2)[Me(HP2O7)(2) center dot 2H(2)O] [Me = Co (1), Ni (2)] have been synthesized and investigated by single-crystal X-ray diffractometry. The two structures resulted to be isostructural within triclinicspace group PT The unit-cell parameters are: a = 7.5211(6) A, b = 7.5574(3) angstrom, c = 9.7689(7) angstrom, a = 103.6(1)degrees, beta = 111.14(1)degrees, gamma = 98.04(1)degrees, V = 486.9(l) angstrom(3) (1) and a = 7.4631(15) angstrom, b = 7.5274(12)angstrom, c = 9.743(3) angstrom, alpha = 104.28(2)degrees, beta = 110.75(2)degrees, gamma = 97.50(2)degrees, V = 481.4(2) angstrom(3) (2). The three-dimensional network is built up by discrete Me(HP2O7)(2) center dot 2H(2)O moieties, which, via strong O-H center dot center dot center dot O bonds, form layers parallel to ab plane. Ethylenediammonium groups are located between such layers, stabilizing the framework via N-H center dot center dot center dot O bonds. The hydrogendiphosphate g

Czech name

Nový isostrukturní ethylendiamonium difosforečnan (NH3(CH2)2NH3)2[Me(HP2O7)2 * 2 H2O] [Me = Co, Ni]: Rtg. strukturí analýza a viblační spektra

Czech description

Nový isostrukturní ethylendiamonium difosforečnan (NH3(CH2)2NH3)2[Me(HP2O7)2 * 2 H2O] [Me = Co, Ni]: Rtg. strukturí analýza a viblační spektra

Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2006

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Zeitschrift für Kristallographie

ISSN

0044-2968

e-ISSN

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Volume of the periodical

9/2006

Issue of the periodical within the volume

221

Country of publishing house

IT - ITALY

Number of pages

7

Pages from-to

649-655

UT code for WoS article

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EID of the result in the Scopus database

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