Crystal Structures of Two Aromatic Zinc(II) Carboxylates: [Zn(4-Chlorosalicylato)(2)(H(2)O)(4)]center dot 2theophylline center dot(H(2)O)(2) and Unique [Zn(5-Chlorosalicylato)(2)(isonicotinamide)(2)(H(2)O)]

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F11%3A39892401" target="_blank" >RIV/00216275:25310/11:39892401 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1007/s10870-011-0049-z" target="_blank" >http://dx.doi.org/10.1007/s10870-011-0049-z</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s10870-011-0049-z" target="_blank" >10.1007/s10870-011-0049-z</a>

Result language
angličtina
Original language name
Crystal Structures of Two Aromatic Zinc(II) Carboxylates: [Zn(4-Chlorosalicylato)(2)(H(2)O)(4)]center dot 2theophylline center dot(H(2)O)(2) and Unique [Zn(5-Chlorosalicylato)(2)(isonicotinamide)(2)(H(2)O)]
Original language description
The crystal structures of two zinc(II) 4-chloroand 5-chlorosalicylate complexes, [Zn(4-ClC(6)H(3)-2-(OH)COO(2)(H(2)O)(4)]center dot 2tph center dot(H(2)O)(2) (I) and [Zn(5-ClC(6)H(3)-2-(OH)COO)(2)(ina)(2)(H(2)O)] (II), where tph is theophylline and ina is isonicotinamide, have been determined using X-ray diffraction methods. Crystals of both (I) and (II) are triclinic, space group P-1, with Z = 1 in a cell with a = 7.2220(3), b = 8.59700(10), c = 16.0210(5) angstrom, alpha = 75.990(2), beta = 83.959(2),gamma = 68.455(2)degrees, V = 897.54(5) angstrom(3) (I) and with Z = 2 in a cell with a = 11.4148(11), b = 11.5327(10), c = 12.0685(13) angstrom, alpha = 63.458(6), beta = 87.547(8), gamma = 89.387(7)degrees, V = 1419.9(2) angstrom(3) (II). The coordination environment of the zinc(II) atom of compound (I) consists of two unidentate carboxylate oxygen atoms and four oxygen atoms of aqua ligands, forming a distorted octahedral configuration. Two theophylline molecules and the remaining wa
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
<a href="/en/project/LC523" target="_blank" >LC523: Perspective inorganic materials</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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