Preparation, Crystal Structure and Spectroscopic Properties of Dimeric [Zn(2-bromobenzoato)(2)(phenazone)](2) and Monomeric [Zn(2-bromobenzoato)(2)(thiourea)(2)]center dot 2H(2)O
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F11%3A00364607" target="_blank" >RIV/61388955:_____/11:00364607 - isvavai.cz</a>
Alternative codes found
RIV/61388980:_____/11:00364607
Result on the web
<a href="http://dx.doi.org/10.1007/s10870-011-0041-7" target="_blank" >http://dx.doi.org/10.1007/s10870-011-0041-7</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s10870-011-0041-7" target="_blank" >10.1007/s10870-011-0041-7</a>
Alternative languages
Result language
angličtina
Original language name
Preparation, Crystal Structure and Spectroscopic Properties of Dimeric [Zn(2-bromobenzoato)(2)(phenazone)](2) and Monomeric [Zn(2-bromobenzoato)(2)(thiourea)(2)]center dot 2H(2)O
Original language description
The binuclear zinc complex bis(2-bromobenzoato- O)-bis(mu(2)-2-bromobenzoato-O,O')-bis(phenazone-O) -dizinc(II) (I) and the mononuclear dihydrate bis(2-bromobenzoato- O)-bis(thiourea-S)-zinc(II) (II) have been synthesized and characterized by means of elemental analysis and spectroscopic methods (IR, (1)H and (13)C NMR, EDS). The solid state structures of both compounds were determined by single-crystal X-ray diffractometry. Compound [Zn(2-BrC(6)H(4)COO)(2)(phen)](2) (phen-phenazone) (I) crystallized asa dimeric compound with a triclinic lattice (space group P - 1), where both zinc atoms, inter-connected by two carboxylate groups, possess a distorted tetrahedral coordination environment. The crystallographic data of complex I: a = 9.9410(3) angstrom,b = 10.7309(3) angstrom, c = 12.9237(4) angstrom, alpha = 93.6004(17)degrees, beta = 92.5898(11)degrees, gamma = 116.2192(16)degrees, V = 1230.26(6) angstrom(3), Z = 1.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Chemical Crystallography
ISSN
1074-1542
e-ISSN
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Volume of the periodical
41
Issue of the periodical within the volume
7
Country of publishing house
US - UNITED STATES
Number of pages
8
Pages from-to
1036-1043
UT code for WoS article
000292841400022
EID of the result in the Scopus database
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