Reactions of P4S10 and pyPS2Cl with N,N-diphenylurea and N,N-diphenylthiourea
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F07%3A00032323" target="_blank" >RIV/00216224:14310/07:00032323 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Reactions of P4S10 and pyPS2Cl with N,N-diphenylurea and N,N-diphenylthiourea
Original language description
The reaction of P4S10 (1) with N,N-diphenylurea (PhNH)2CO (2) results in new heterocyclic compounds containing the (PSN)2 cycle and the cyclic thiophosphates [pyH]2[P2S8] (5), [pyH]2[P2S7] (6) and [pyH]3[P3S9] (7). A similar reaction, but carried out with N,N -diphenylthiourea (PhNH)2CS (8), leads to the formation of 4 and 6. pyPS2Cl (9), used as an alternative starting material, also yields compounds 3, 4, 5, and further [pyH][PS2Cl2] (10) and S8 after reaction with 2. Compound 3 reacts with Pd(CH3COO)2, with the formation of the complex [Pd(Ph2N2COPS2)2] (11). The crystal structures of 3 and 7 were determined by single crystal X-ray diffraction.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
S - Specificky vyzkum na vysokych skolach
Others
Publication year
2007
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Polyhedron
ISSN
0277-5387
e-ISSN
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Volume of the periodical
2007
Issue of the periodical within the volume
26
Country of publishing house
CZ - CZECH REPUBLIC
Number of pages
7
Pages from-to
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UT code for WoS article
000249905900028
EID of the result in the Scopus database
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