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A peculiar bonding of sulphur at the Nb(001) surface

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F08%3A00024421" target="_blank" >RIV/00216224:14310/08:00024421 - isvavai.cz</a>

  • Alternative codes found

    RIV/68081723:_____/08:00318091

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    A peculiar bonding of sulphur at the Nb(001) surface

  • Original language description

    The morphological, crystallographical and electronic structure of a well-ordered pseudomorphic sulphur monolayer (S ML) bonded at the (001) surface of a niobium substrate was investigated experimentally and theoretically. The system exhibits strong sulphur-niobium bonds with fourfold symmetry which do not exist in bulk niobium chalcogenides. These bonds enhance the localization of occupied bands near the Fermi energy in two Nb MLs under the S ML and, due to changed symmetry and stoichiometry, push the p-states of the S ML to deeper binding energies as compared to Nb chalcogenides. The S ML shows strong iono-covalent bonding to Nb(001) with bonding states mainly due to S-3p and antibonding states due to Nb-4d orbitals.

  • Czech name

    Zvláštní vazba síry na povrchu Nb(001

  • Czech description

    Teoreticky a experimentálně byla studována morfologická, krystalografická a elektronová struktura monovrstvy síry na povrchu Nb(001). Byla prokázána existence čtyřčetných vazeb mezi atomy síry a niobu, které zvyšují lokalizaci obsazených pásů blízko Fermiho energie ve dvou povrchových vrstvách Nb pod monovrstvou síry a posouvají p-stavy síry k hlubším energiím ve srovnání s chalkogenidy niobu. Monovrstva síry vykazuje silnou iontově-kovalentní vazbu k povrchu Nb(001), přičemž vazebné stavy jsou tvořenyhlavně 3-p stavy síry a antivazebné 4d stavy niobu.

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    BM - Solid-state physics and magnetism

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2008

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Europhysics letters

  • ISSN

    0295-5075

  • e-ISSN

  • Volume of the periodical

    83

  • Issue of the periodical within the volume

    July 2008

  • Country of publishing house

    FR - FRANCE

  • Number of pages

    6

  • Pages from-to

  • UT code for WoS article

    000259021200013

  • EID of the result in the Scopus database