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First-principles study of magnetism at grain boundaries in iron and nickel

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F08%3A00024422" target="_blank" >RIV/00216224:14310/08:00024422 - isvavai.cz</a>

  • Alternative codes found

    RIV/68081723:_____/08:00318090

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    First-principles study of magnetism at grain boundaries in iron and nickel

  • Original language description

    The geometric and magnetic structures of fully relaxed symmetrical tilt Sigma5(310) grain boundaries (GBs) in iron and Sigma5(210) GBs in nickel have been investigated using density-functional theory. We found for both GBs an enhancement of the local magnetic moments of atoms in the GB plane (2.55 mu_B for iron and 0.67 mu_B for nickel) which is correlated with the larger local atomic volume compared to the bulk. At larger distances from the GB the variation of the local magnetic moments follows the changes in the exchange splitting in the spin-polarized local density of states imposed by the local variations in the atomic geometry. When Si and Sn impurity atoms in interstitial or substitutional positions appear at the Sigma 5(310) GB in iron, the local magnetic moments of iron atoms are reduced for silicon and almost unchanged for tin.We also calculated the segregation enthalpies of both impurities and confirmed the experimental fact that silicon is a substitutional and tin an interst

  • Czech name

    Studium magnetismu na hranicích zrn v železe a niklu z prvních pricipů

  • Czech description

    Geometrická a magnetická struktura plně relaxovaných symetrických sklonových hranic zrn (GB) Sigma5(310) v železe a Sigma5(210) v niklu byla studována pomocí prvoprincipielních výpočtů elektronové struktury. Byl zjištěn zřetelný nárůst magnetického momentu na obou hranicích zrn.

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    BM - Solid-state physics and magnetism

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2008

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Physical Review B

  • ISSN

    1098-0121

  • e-ISSN

  • Volume of the periodical

    78

  • Issue of the periodical within the volume

    5

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    10

  • Pages from-to

  • UT code for WoS article

    000259368200074

  • EID of the result in the Scopus database