Phosphoric ligands immobilized on polymeric resins
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F08%3A00025415" target="_blank" >RIV/00216224:14310/08:00025415 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
čeština
Original language name
Phosphoric ligands immobilized on polymeric resins
Original language description
Hydrogen cyanide (HCN) addition is chemical reaction taking important part in chemical industry over the world. HCN addition reactions are one the most used synthetic routes leading to cyano compounds which are indispensable materials for pharmaceuticalindustry and chemical industry itself as well. The key role in HCN additions is represented by the catalytic system present in reaction mixtures, which increases yields and purity of desired product and decreases energetic and material demands of the reaction at the same time. It is known that Ni(0)-complexes stand as the most used catalysts in such mixtures having high efficiency and selectivity, although catalytic system may be rather complicated and the resulting product can be dependent on many factors. Some disadvantages of such homogenous catalytic systems could be eliminated using immobilized Ni-complexes as catalysts. First step in this approach is to prepare phosphoric ligands immobilized on suitable polymeric resin.
Czech name
Phosphoric ligands immobilized on polymeric resins
Czech description
Hydrogen cyanide (HCN) addition is chemical reaction taking important part in chemical industry over the world. HCN addition reactions are one the most used synthetic routes leading to cyano compounds which are indispensable materials for pharmaceuticalindustry and chemical industry itself as well. The key role in HCN additions is represented by the catalytic system present in reaction mixtures, which increases yields and purity of desired product and decreases energetic and material demands of the reaction at the same time. It is known that Ni(0)-complexes stand as the most used catalysts in such mixtures having high efficiency and selectivity, although catalytic system may be rather complicated and the resulting product can be dependent on many factors. Some disadvantages of such homogenous catalytic systems could be eliminated using immobilized Ni-complexes as catalysts. First step in this approach is to prepare phosphoric ligands immobilized on suitable polymeric resin.
Classification
Type
D - Article in proceedings
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/2A-1TP1%2F090" target="_blank" >2A-1TP1/090: New catalysts and reagents for sustainable green syntheses and combinatorial syntheses</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2008
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Article name in the collection
ECSOC 12: http://www.usc.es/congresos/ecsoc/12/ECSOC12.htm; CD version
ISBN
3-906980-20-0
ISSN
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e-ISSN
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Number of pages
7
Pages from-to
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Publisher name
Molecular Diversity Preservation International (MDPI), Kandererstrasse 25, CH-4057 Basel, Switzerland
Place of publication
Basel, Switzerland
Event location
http://www.usc.es/congresos/ecsoc/12/ECSOC12.htm
Event date
Jan 11, 2008
Type of event by nationality
WRD - Celosvětová akce
UT code for WoS article
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