Synthesis, spectroscopic and X-ray characterization of new molecular organotitanium(IV) phosphonate

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F08%3A00025750" target="_blank" >RIV/00216224:14310/08:00025750 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Synthesis, spectroscopic and X-ray characterization of new molecular organotitanium(IV) phosphonate

Original language description

Dititanate [{Ti(C5Me4Et)(O2P(OH)Me)(O2P(O)Me)}2] (1) was prepared from (C5Me4Et)TiF3 and MeP(O)(OSiMe3)2. The molecular structure of the compound 1 has been determined by single-crystal X-ray diffraction analysis. In the cage cluster, two titanium atomsare bridged by two bidentate monoanionic and by two bidentate dianionic methylphosphonate groups. The OH groups of the monoanionic phosphonates and oxygen atoms of the dianionic phosphonates are connected by strong intramolecular hydrogen bonds. The NMRspectroscopy reveals the fast proton migration within the hydrogen bond.

Czech name

Syntéza, spektroskopická a strukturní charakterizace nového molekulárního fosfonátu titaničitého

Czech description

Syntéza, spektroskopická a strukturní charakterizace nového molekulárního fosfonátu titaničitého.

Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2008

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Inorganic Chemistry Communication

ISSN

1387-7003

e-ISSN

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Volume of the periodical

11

Issue of the periodical within the volume

1

Country of publishing house

NL - THE KINGDOM OF THE NETHERLANDS

Number of pages

3

Pages from-to

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UT code for WoS article

000253105200002

EID of the result in the Scopus database

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