Diaquabis(1,10-phenanthroline-k2 N,N')manganese(II) thiodiglycolate bis(1,10-phenanthroline-k2 N,N')(thiodiglycolato-k2 O,O')manganese(II) tridecahydrate
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15410%2F03%3A00001448" target="_blank" >RIV/61989592:15410/03:00001448 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Diaquabis(1,10-phenanthroline-k2 N,N')manganese(II) thiodiglycolate bis(1,10-phenanthroline-k2 N,N')(thiodiglycolato-k2 O,O')manganese(II) tridecahydrate
Original language description
The title compound, [Mn(C12H8N2)(2)(H2O)(2)](C4H4O4S).-[Mn(C4H4O4S)(C12H8N2)(2)].13H(2)O, contains one dianion of thiodiglycolic acid (tdga(2-)) and two independent manganese(II) moieties, viz. [Mn(phen)(2)(H2O)(2)](2+) and [Mn(tdga)(phen)(2)], where phen is 1,10-phenanthroline. The Mu(II) atoms are octahedrally coordinated by four N atoms of two bidentate phen ligands [Mn-N = 2.240 (2)-2.3222 (19) Angstrom] and either two water O atoms or two tdga carboxyl O atoms [Mn-O = 2.1214 (17)-2.1512 (17) Angstrom]. The tdga ligand chelates as an O,O'-bidentate ligand, forming an eight-membered ring with one Mn atom. The free tdga2- dianion is hydrogen bonded to an [Mn(phen)(2)(H2O)(2)](2+) ion, with O...O distances of 2.606 (2) and 2.649 (2) Angstrom. The crystal structure is further stabilized by an extensive network of hydrogen bonds involving 13 water molecules.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2003
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Acta Crystallographica Section C-crystal Structure Communications
ISSN
0108-2701
e-ISSN
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Volume of the periodical
59
Issue of the periodical within the volume
11
Country of publishing house
DK - DENMARK
Number of pages
3
Pages from-to
"M429"-"M431"
UT code for WoS article
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EID of the result in the Scopus database
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