Bis(4,7-dichloro-1,10-phenanthroline-kappa N-2,N ')bis(dicyanamido-kappa N)copper(II)

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F10%3A10214987" target="_blank" >RIV/61989592:15310/10:10214987 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
Bis(4,7-dichloro-1,10-phenanthroline-kappa N-2,N ')bis(dicyanamido-kappa N)copper(II)
Original language description
In the title compound, [Cu(C2N3)(2)(C12H6Cl2N2)(2)], the Cu-II atom is coordinated by two chelating 4,7-dichloro-1,10-phenanthroline (4,7-Cl-phen) ligands and two dicyanamide (dca) ligands in a cis arrangement, forming a distorted octahedral geometry. The equatorial plane is occupied by three N atoms from two 4,7-Cl-phen ligands and one N atom from a dca ligand at shorter Cu-N distances. Due to the Jahn-Teller effect, the axial positions are occupied by a 4,7-Cl-phen N atom and a dca N atom at longer Cu-N distances. The dca ligands are nearly planar, with maximum deviations of 0.006 (1) angstrom.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Publication year
2010
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical
Acta Crystallographica Section E - Structure Reports Online
ISSN
1600-5368
e-ISSN
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Volume of the periodical
66
Issue of the periodical within the volume
6
Country of publishing house
DK - DENMARK
Number of pages
2
Pages from-to
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UT code for WoS article
000278263300088
EID of the result in the Scopus database
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