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Magnetic coupling in EE and EO azido-bridged binuclear copper complexes: Synthesis, structure and magnetic studies

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F10%3A00044020" target="_blank" >RIV/00216224:14310/10:00044020 - isvavai.cz</a>

  • Alternative codes found

    RIV/61989592:15310/10:10212123

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Magnetic coupling in EE and EO azido-bridged binuclear copper complexes: Synthesis, structure and magnetic studies

  • Original language description

    Four azide bridged dinuclear copper(II) complexes have been synthesized, out of which complexes 1 and 2 have been characterized structurally. In Complex 1 the two bridging azide ligands have connected the two metal centers in an end-on (EO) fashion withaSP (asymmetric Square Pyramidal) geometry and showed an weak antiferromagnetic interaction. On the contrary, in complex 2, the two metal centers have been connected in end-to-end (EE) fashion exhibiting moderately strong ferromagnetic interaction. Cyclic voltammetric studies performed on all the four complexes show a reasonably good correlations.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2010

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Polyhedron

  • ISSN

    0277-5387

  • e-ISSN

  • Volume of the periodical

    29

  • Issue of the periodical within the volume

    4

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    8

  • Pages from-to

  • UT code for WoS article

    000276000900002

  • EID of the result in the Scopus database