Two coordination polymers based on semicarbazone Schiff base and azide: synthesis, crystal structure, electrochemistry, magnetic properties and biological activity
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F13%3A00397932" target="_blank" >RIV/68378271:_____/13:00397932 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1080/00958972.2013.764413" target="_blank" >http://dx.doi.org/10.1080/00958972.2013.764413</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1080/00958972.2013.764413" target="_blank" >10.1080/00958972.2013.764413</a>
Alternative languages
Result language
angličtina
Original language name
Two coordination polymers based on semicarbazone Schiff base and azide: synthesis, crystal structure, electrochemistry, magnetic properties and biological activity
Original language description
Two coordination polymers [Mn(L)(?1,1?N3)2]2n.[Mn(H2O)2(?1,1?N3)2]n (1) and [Cd(HL)(?1,1?N3)2]n (2) have been synthesized from pyridine-2-carbaldehyde semicarbazone (HL) and azide ligands, characterized by FT-IR, UV?vis spectroscopy and X-ray crystallography. Single crystal X-ray diffraction revealed that 1 is a coordination polymer consisting of two infinite 1-D chains, where Mn centers are connected via two double end-on (EO) azide bridges. 2 is a coordination polymer consisting of a 1-D infinite chain, where Cd centers are connected via two double EO azide bridges. The electrochemistry of HL, 1 and 2! was studied by cyclic voltammetry. Magnetic susceptibility measurements indicate bulk ferromagnetic coupling for 1 below 5K. Antimicrobial activitiesof both compounds 1 and 2 were investigated.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CB - Analytical chemistry, separation
OECD FORD branch
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Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Coordination Chemistry
ISSN
0095-8972
e-ISSN
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Volume of the periodical
66
Issue of the periodical within the volume
5
Country of publishing house
GB - UNITED KINGDOM
Number of pages
15
Pages from-to
748-762
UT code for WoS article
000320914400002
EID of the result in the Scopus database
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