Metal-dependent assembly of a tetranuclear copper(II) complex versus a 1D chain coordination polymer of cobalt(III) complex with N2O2-chelating Schiff-base ligand: Synthesis, characterization and crystal structures

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F10%3A00348567" target="_blank" >RIV/68378271:_____/10:00348567 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Metal-dependent assembly of a tetranuclear copper(II) complex versus a 1D chain coordination polymer of cobalt(III) complex with N2O2-chelating Schiff-base ligand: Synthesis, characterization and crystal structures

Original language description

By changing metal ions in the presence of N2O2-chelating Schiff-base ligand sal2hn [sal2hn = N,N'-bis(salicylidene)-1,2-diaminocyclohexane] and a large excess of NaN3, tetranuclear copper(II) complex [Cu4(?-sal2hn)2(?1,1-N3)2(N3)2] (1) and 1D chain coordination polymer of cobalt(III) complex {Na[Co(?-sal2hn)(?1,1-N3)(N3)(H2O)(?-O)}n(2) have been successfully obtained. Single-crystal X-ray analyses revealed that in complex 1 the copper(II) ions are bridged alternately by azido and phenoxo-sal2hn ligands,while in complex 2 the cobalt(III) and sodium ions are bridged alternately by azido and phenoxo-sal2hn ligands and sodium ions are linked together by O atoms to form polymeric chain.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

BM - Solid-state physics and magnetism

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2010

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Polyhedron

ISSN

0277-5387

e-ISSN

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Volume of the periodical

29

Issue of the periodical within the volume

2

Country of publishing house

NL - THE KINGDOM OF THE NETHERLANDS

Number of pages

6

Pages from-to

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UT code for WoS article

000275020700019

EID of the result in the Scopus database

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