Anion-Dependent Facile Route to Magnetic Dinuclear and Dodecanuclear Cobalt Clusters
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F10%3A10213070" target="_blank" >RIV/61989592:15310/10:10213070 - isvavai.cz</a>
Result on the web
—
DOI - Digital Object Identifier
—
Alternative languages
Result language
angličtina
Original language name
Anion-Dependent Facile Route to Magnetic Dinuclear and Dodecanuclear Cobalt Clusters
Original language description
An unprecedented dodecanuclear CoIII3CoII9 and a dinuclear CoII2 cluster were synthesized facilely from reactions of different cobalt(II) salts with the ligand (1H-benzimidazol-2-yl)-methanol. The cobalt ions in the Co12 supercluster are linked into a disclike structures through mý3-OL, mý-OL, mý3-O2-, mý1,1-N3- and mý1,1,1-N3- bridges. Magnetic studies reveal that strong ferromagnetic coupling through double end-on (EO) azido bridges exists in 1, while both ferromagnetic coupling through the mý3-OL andmý-OL pathways and antiferromagnetic coupling through the mý1,1,1-N3- pathway exist in 2, which results in a ferrimagnetic behaviour of 2.
Czech name
—
Czech description
—
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
—
Result continuities
Project
—
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2010
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
European Journal of Inorganic Chemistry
ISSN
1434-1948
e-ISSN
—
Volume of the periodical
2010
Issue of the periodical within the volume
15
Country of publishing house
DE - GERMANY
Number of pages
5
Pages from-to
—
UT code for WoS article
000278611600003
EID of the result in the Scopus database
—