Supramolecular solid-state architectures constructed from 4,4-bipyridine-N,N-dioxide and dicyanamido tectons. Synthesis and crystal structures of [M(bpno)2{N(CN)2}2(H2O)2]

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F03%3A00007959" target="_blank" >RIV/00216224:14310/03:00007959 - isvavai.cz</a>
Result on the web
—
DOI - Digital Object Identifier
—

Result language
angličtina
Original language name
Supramolecular solid-state architectures constructed from 4,4-bipyridine-N,N-dioxide and dicyanamido tectons. Synthesis and crystal structures of [M(bpno)2{N(CN)2}2(H2O)2]
Original language description
The reaction between transition metal salts, M(ClO4 )2.6H2O (M = Co, Mn, Cu), sodium dicyanamide, NaN(CN)2 , and 4,4-bipyridine-N,N-dioxide, bpno, leads to three new complexes: [Co(bpno)2{N(CN)2}2(H2O)2] 1, [Mn(bpno)2{N(CN)2}2(H2O)2]2, and [Cu(bpno){N(CN)2}2(H2O)] 3. In the three compounds, the N(CN)2 ions act as monodentate ligands through one of the CN groups. Compounds 1 and 2 are isomorphous. Both bpno molecules are terminal ligands. The metal ions, cobalt(II) and manganese(II), display an octahedral stereochemistry and are located on an inversion center. In compound 3, the bpno molecules act as bridging ligands and support the formation of infinite chains. The copper(II) ions are pentacoordinated. The packing diagrams of the three compounds revealinteresting supramolecular solid-state architectures. Compounds 1 and 2 are two-dimensional hydrogen bonded polymers, which are formed by the interaction of the bpno and dicyanamido ligands with the aqua ligands of neighboring [M(bpno)2{
Czech name
—
Czech description
—

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
—

Project
<a href="/en/project/GA203%2F01%2F1533" target="_blank" >GA203/01/1533: New Nonaqueous Routes to Phosphate, Silicate, Hybrid, and Oxide Materials</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2003
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Similar results(10)