Hexacyanochromates(III) and Hexacyanocobaltates(III) of Copper(II) with Tridentate and Tetradentate N-donor Ligands. Crystal Structure of [{Cu(ept)}3{Co(CN)6}2] H2O (ept = N-(2-aminoethyl)-1,3-propandiamine)

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27640%2F09%3A00021842" target="_blank" >RIV/61989100:27640/09:00021842 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Hexacyanochromates(III) and Hexacyanocobaltates(III) of Copper(II) with Tridentate and Tetradentate N-donor Ligands. Crystal Structure of [{Cu(ept)}3{Co(CN)6}2] H2O (ept = N-(2-aminoethyl)-1,3-propandiamine)

Original language description

The following complexes [{Cu(ept)}3{Cr(CN)6}2] 5H2O, [{Cu(hatce)}3{Cr(CN)6}2] 15H2O, [{Cu(hatco)}3{Cr(CN)6}2] 14H2O, [{Cu(ept)}3{Co(CN)6}2] 5H2O, [{Cu(hatce)}3{Co(CN)6}2] 18H2O and [{Cu(medpt)}3{Co(CN)6}2] H2O (ept = N-(2-aminoethyl)-1,3-propandiamine, hatce = 1,3,6,10,12,15-hexaazatricyclo[13.3.1.16,10]eicosane, hatco = 1,3,6,9,11,14-hexaazatricyclo[12.2.1.16,9]octadecane and medpt = N,N-bis-(3-aminopropyl)methylamine) have been synthesized by the reactions of Cu(ClO4)2 6H2O or Cu(NO3)2 3H2O and ept ormedpt, or [Cu(hatce)](ClO4)2 2H2O and [Cu(hatco)Cl]ClO4 H2O, and K3[Cr(CN)6] or K3[Co(CN)6] in aqueous solution, respectively. All the compounds have been characterized by elemental analyses, IR and UV-Vis spectroscopies and magnetic measurements and the three selected complexes were studied using thermal analysis. The crystal structure of [{Cu(ept)}3{Co(CN)6}2] H2O has been determined by single-crystal X-ray analysis - the studied compound can be formulated as [{Cu(ept)}6{Co(CN)6}3][Co

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CC - Organic chemistry

OECD FORD branch

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Project

<a href="/en/project/GA205%2F08%2F0869" target="_blank" >GA205/08/0869: Clay minerals as host matrices for functional nanostructures</a><br>

Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2009

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Pol.Journal Chem.

ISSN

0137-5083

e-ISSN

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Volume of the periodical

83

Issue of the periodical within the volume

10

Country of publishing house

PL - POLAND

Number of pages

10

Pages from-to

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UT code for WoS article

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EID of the result in the Scopus database

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