Hexacyanochromates(III) and Hexacyanocobaltates(III) of Copper(II) with Tridentate and Tetradentate N-donor Ligands. Crystal Structure of [{Cu(ept)}(3){Co(CN)(6)}(2)]center dot H2O (ept = N-(2-aminoethyl)-1,3-propandiamine)
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F09%3A00010165" target="_blank" >RIV/61989592:15310/09:00010165 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Hexacyanochromates(III) and Hexacyanocobaltates(III) of Copper(II) with Tridentate and Tetradentate N-donor Ligands. Crystal Structure of [{Cu(ept)}(3){Co(CN)(6)}(2)]center dot H2O (ept = N-(2-aminoethyl)-1,3-propandiamine)
Original language description
The following complexes [{Cu(ept)}(3) {Cr(CN)(6)}(2)]center dot 5H(2)O, [{Cu(hatce)}(3){Cr(CN)(6))2]center dot 15H(2)O, [{Cu(hatce))(3){Cr(CN)(6)}(2)]center dot 14H(2)O,[{Cu(ept)}(3){Co(CN)(6)}(2)]center dot 5H(2)O, [{Cu(hatce)}(3){Co(CN)(6)}(2)]center dot 18H(2)O and [{Cu(medpt)}(3){Co(CN)(6)}(2)]center dot H2O (ept = N-(2-aminoethyl)-1,3-propandiamine, hatce = 1,3,6,10,12,15-hexaazatricyclo [13.3.1.1(6,10)]cicosane, hatco= 1,3,6,9,11,14-hexaazatricyclo[12.2.1.1(6,9)]octadccane and medpt = N,N-bis-(3-aminopropyl) m ethyl amine) have been synthesized by the reactions Of Cu(ClO4)(2)center dot 6H(2)O or Cu(NO3)(2)center dot 3H(2)O and ept or medpt, or [Cu(hatce)](ClO4)(2)-2H(2)O and [Cu(hatco)Cl]ClO4 center dot H2O, and K-3[Cr(CN)(6)] or K-3[Co(CN)(6)] in aqueous solution, respectively. All the compounds have been characterized by elemental analyses, IR and UV-Vis spectroscopies and magnetic measurements and the three selected complexes were studied using thermal analysis. The crystal st
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
S - Specificky vyzkum na vysokych skolach
Others
Publication year
2009
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Polish Journal of Chemistry
ISSN
0137-5083
e-ISSN
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Volume of the periodical
83
Issue of the periodical within the volume
10
Country of publishing house
PL - POLAND
Number of pages
10
Pages from-to
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UT code for WoS article
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EID of the result in the Scopus database
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