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Hexacyanochromates(III) and Hexacyanocobaltates(III) of Copper(II) with Tridentate and Tetradentate N-donor Ligands. Crystal Structure of [{Cu(ept)}(3){Co(CN)(6)}(2)]center dot H2O (ept = N-(2-aminoethyl)-1,3-propandiamine)

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F09%3A00010165" target="_blank" >RIV/61989592:15310/09:00010165 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Hexacyanochromates(III) and Hexacyanocobaltates(III) of Copper(II) with Tridentate and Tetradentate N-donor Ligands. Crystal Structure of [{Cu(ept)}(3){Co(CN)(6)}(2)]center dot H2O (ept = N-(2-aminoethyl)-1,3-propandiamine)

  • Original language description

    The following complexes [{Cu(ept)}(3) {Cr(CN)(6)}(2)]center dot 5H(2)O, [{Cu(hatce)}(3){Cr(CN)(6))2]center dot 15H(2)O, [{Cu(hatce))(3){Cr(CN)(6)}(2)]center dot 14H(2)O,[{Cu(ept)}(3){Co(CN)(6)}(2)]center dot 5H(2)O, [{Cu(hatce)}(3){Co(CN)(6)}(2)]center dot 18H(2)O and [{Cu(medpt)}(3){Co(CN)(6)}(2)]center dot H2O (ept = N-(2-aminoethyl)-1,3-propandiamine, hatce = 1,3,6,10,12,15-hexaazatricyclo [13.3.1.1(6,10)]cicosane, hatco= 1,3,6,9,11,14-hexaazatricyclo[12.2.1.1(6,9)]octadccane and medpt = N,N-bis-(3-aminopropyl) m ethyl amine) have been synthesized by the reactions Of Cu(ClO4)(2)center dot 6H(2)O or Cu(NO3)(2)center dot 3H(2)O and ept or medpt, or [Cu(hatce)](ClO4)(2)-2H(2)O and [Cu(hatco)Cl]ClO4 center dot H2O, and K-3[Cr(CN)(6)] or K-3[Co(CN)(6)] in aqueous solution, respectively. All the compounds have been characterized by elemental analyses, IR and UV-Vis spectroscopies and magnetic measurements and the three selected complexes were studied using thermal analysis. The crystal st

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2009

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Polish Journal of Chemistry

  • ISSN

    0137-5083

  • e-ISSN

  • Volume of the periodical

    83

  • Issue of the periodical within the volume

    10

  • Country of publishing house

    PL - POLAND

  • Number of pages

    10

  • Pages from-to

  • UT code for WoS article

  • EID of the result in the Scopus database