Synthesis, structure and magnetic behaviour of a two dimensional cyano-bridged complex [{Cu(ept)}(3)Fe(CN)(6)] (ClO4)(2)center dot 5H(2)O [ept = N-(2-aminoethyl)-1,3 diaminopropane]
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F01%3A00001667" target="_blank" >RIV/61989592:15310/01:00001667 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Synthesis, structure and magnetic behaviour of a two dimensional cyano-bridged complex [{Cu(ept)}(3)Fe(CN)(6)] (ClO4)(2)center dot 5H(2)O [ept = N-(2-aminoethyl)-1,3 diaminopropane]
Original language description
The bimetallic compound [{Cu(ept)}(3)Fe(CN)(6)](ClO4)(2). 5H(2)O [ept = N-(2-aminoethyl)-1,3-diaminopropane] has been prepared from the reaction of Cu(ClO4)(2). 6H(2)O, ept and K-4[Fe(CN)(6)]. 3H(2)O in water and its crystal and molecular structure has been determined. The structure consists of a two-dimensional network formed by [{Cu(ept)}(3)Fe(CN)(6)](2+) moieties, perchlorate anions and water molecules. Every [Fe(CN)(6)](4-) anion is coordinated by six [Cu(ept)](2+) cations through six cyano nitrogens, providing a 2D sheet structure extended by Fe-(CN)-Cu linkages. All the copper(II) ions are five-coordinated by three ept nitrogen and two cyanide nitrogen atoms in a distorted square-pyramidal arrangement. The EPR spectrum of the compound at room temperature also confirms the coordination environment of the copper(II) atoms. A magnetic susceptibility measurement of the complex was performed down to 4 K but no coupling was found among the copper atoms via the -(NC)-Fe-(CN)- bridges.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2001
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
New Journal of Chemistry
ISSN
1144-0546
e-ISSN
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Volume of the periodical
25
Issue of the periodical within the volume
4
Country of publishing house
FR - FRANCE
Number of pages
4
Pages from-to
655-658
UT code for WoS article
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EID of the result in the Scopus database
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