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Study of dehalogenation of halogenoanilines using Raney Al-Ni alloy in aqueous medium at room temperature

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F10%3A00044583" target="_blank" >RIV/00216224:14310/10:00044583 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216275:25310/10:39882234

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Study of dehalogenation of halogenoanilines using Raney Al-Ni alloy in aqueous medium at room temperature

  • Original language description

    Dehalogenation of halogenated anilines by action of powdered aluminium-nickel alloy in aqueous alkaline solution at room temperature has been studied. The reaction course was monitored by means of 1H nuclear magnetic resonance (NMR) spectroscopy. The rates of dehalogenation of 4-bromo-, 4-chloro-, 4-fluoro- and 3-chloroaniline were compared under conditions of minimum necessary excess of Al-Ni alloy as reducing agent in edetane buffer medium at pH 10.9. On the basis of the results obtained in buffers, the dehalogenation method of aqueous solutions of halogenoanilines was verified using NaOH as the base.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CC - Organic chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GP203%2F07%2FP248" target="_blank" >GP203/07/P248: Bimetallic alloys combined with humic acids for contaminated water treatment</a><br>

  • Continuities

    S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2010

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Monatshefte fuer Chemie, Chemical Monthly

  • ISSN

    0026-9247

  • e-ISSN

  • Volume of the periodical

    141

  • Issue of the periodical within the volume

    9

  • Country of publishing house

    CZ - CZECH REPUBLIC

  • Number of pages

    6

  • Pages from-to

  • UT code for WoS article

    000281106200013

  • EID of the result in the Scopus database