Study of Reactivity of 4-Halogenoanilines with Metals and Metallic Alloys in Alkaline Aqueous Solution at Room Temperature

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F09%3A00008645" target="_blank" >RIV/00216275:25310/09:00008645 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Study of Reactivity of 4-Halogenoanilines with Metals and Metallic Alloys in Alkaline Aqueous Solution at Room Temperature

Original language description

This article describes a new simple method for dehalogenation of 4-halogenoanilines in buffered aqueous solution using a reduction technique based on the treatment with the metallic alloy in alkaline conditions at room temperature. Al and Zn metals and Al-Fe, Al-Ni, Cu-Sn, Cu-Zn and Al-Cu-Zn metallic alloys were tested as the reductants. The GC-MS and 1H NMR spectroscopy were used for analyzing the reaction mixtures, and aniline was detected as the single product of the reduction of mentioned 4-halogenoanilines. It was observed that the addition of the metal chelating agent is essentioal for the complete dehalogenation of halogenated anilines in buffered solutions. The possibility of lowering of aniline and Ni2+ content in the aqueous solution was tested using flocculation and extraction

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CI - Industrial chemistry and chemical engineering

OECD FORD branch

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Project

<a href="/en/project/GP203%2F07%2FP248" target="_blank" >GP203/07/P248: Bimetallic alloys combined with humic acids for contaminated water treatment</a><br>

Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2009

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Scientific Papers of the University of Pardubice, Series A

ISSN

1211-5541

e-ISSN

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Volume of the periodical

2009

Issue of the periodical within the volume

1

Country of publishing house

CZ - CZECH REPUBLIC

Number of pages

8

Pages from-to

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UT code for WoS article

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EID of the result in the Scopus database

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