Robust 1D open rack-like architecture in coordination polymers of Anderson POMs [{Na-4(H2O)(14)}{Cu(gly)}(2)][TeMo6O24] and [{Cu(en)(2)}(3){TeW6O24}]: synthesis, characterization and heterogeneous catalytic epoxidation of olefines
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F10%3A00047842" target="_blank" >RIV/00216224:14310/10:00047842 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Robust 1D open rack-like architecture in coordination polymers of Anderson POMs [{Na-4(H2O)(14)}{Cu(gly)}(2)][TeMo6O24] and [{Cu(en)(2)}(3){TeW6O24}]: synthesis, characterization and heterogeneous catalytic epoxidation of olefines
Original language description
Two novel organic-inorganic hybrid tungsto-and molybdo-telurates having formula [{Na-4(H2O)(14)}{Cu(gly)}(2)][TeMo6O24] (1){gly = glycine} and [{Cu(en)(2)}(3){TeW6O24}]center dot 6H(2)O {en = ethyline-diamine} (2) based on Anderson type heteropolyoxometalates (POMs) have been synthesized and characterized by X-ray crystallography. Common structural feature of both 1 and 2 is the presence of a unique 1D open rack-like architecture, where the disc shaped Anderson POMs act as steps and cationic Cu-organiccomplexes act as handles of the rack. In 1 the independent structural unit is a 1D coordination polymer with the above mentioned rack type architecture, while in 2, these independent rack-like architectures are further extended to a 2D coordination polymer. Heterogeneous catalysis for the epoxidation of cyclohexene and styrene by complexes 1 and 2 showed very good catalytic efficiency.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)<br>S - Specificky vyzkum na vysokych skolach
Others
Publication year
2010
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Dalton transactions : an international journal of inorganic chemistry
ISSN
1477-9226
e-ISSN
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Volume of the periodical
39
Issue of the periodical within the volume
48
Country of publishing house
CZ - CZECH REPUBLIC
Number of pages
9
Pages from-to
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UT code for WoS article
000284777500008
EID of the result in the Scopus database
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