Allenyloxime - A New Versatile Precursor for the Synthesis of Heterocycles
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F10%3A00048789" target="_blank" >RIV/00216224:14310/10:00048789 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Allenyloxime - A New Versatile Precursor for the Synthesis of Heterocycles
Original language description
We have developed a new methodology for synthesis of diverse heterocyclic compounds based on a simple starting material. Selected allenyloximes shoved high reactivity toward heterocyclizations when exposed to different reaction conditions. Cyclic nitrones bearing various functional groups at positions 2 and 5 were generated. Obtained products were isolated, fully characterized or served as key intermediates for further modification of nitrone skeleton in effective one-pot domino reactions. Additionally,a chemistry of selected cyclic products was explored. Prepared nitrones underwent 1,3-dipolar cycloadditions and with several reactive dipolarophiles formed corresponding products.
Czech name
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Czech description
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Classification
Type
O - Miscellaneous
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA203%2F09%2F1345" target="_blank" >GA203/09/1345: Allenyl synthon in synthesis of heterocyclic compounds</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2010
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů