1,3-Dipolar cycloadditions of new 2,5-bifunctionalized 5-membered cyclic nitrones

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F12%3A00057328" target="_blank" >RIV/00216224:14310/12:00057328 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.tet.2012.01.043" target="_blank" >http://dx.doi.org/10.1016/j.tet.2012.01.043</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.tet.2012.01.043" target="_blank" >10.1016/j.tet.2012.01.043</a>

Result language
angličtina
Original language name
1,3-Dipolar cycloadditions of new 2,5-bifunctionalized 5-membered cyclic nitrones
Original language description
A new family of 5-membered cyclic nitrones bearing functional groups at positions 2,5 were tested in 1,3-cycloadditions with various dipolarophiles. Studied reactions offered corresponding cycloaducts as single diastereomers in high yields. The reactionscope was examined, 23 compounds were isolated and fully characterized. The comparison of the reactivity was done by a study of reaction conversions while different nitrones or dipolarophiles were used. In addition, we have studied the exceptional reactivity of nitrone bearing benzylamino group in position 2. The formation of nitrone complex and evaluation of its reactivity in 1,3-DC is presented.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
—

Project
<a href="/en/project/GA203%2F09%2F1345" target="_blank" >GA203/09/1345: Allenyl synthon in synthesis of heterocyclic compounds</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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